Title: Synthesis of New Alkanediamine Schiff Bases Containing an Ester Function. Preparation and Characterization of Ni<sup>II</sup> Complex with 1,3-Trimethylenediamine Schiff Base
Abstract:Abstract Schiff bases obtained by reaction between β-ketoester ethyl-α-ketocyclopentylcarboxylate (C8H12O3) and various aliphatic diamines NH2(CH2)nNH2, where n = 2, 3, 4, were prepared and studied. A...Abstract Schiff bases obtained by reaction between β-ketoester ethyl-α-ketocyclopentylcarboxylate (C8H12O3) and various aliphatic diamines NH2(CH2)nNH2, where n = 2, 3, 4, were prepared and studied. Also prepared was the complex of NiII and the Schiff base of 1,3-trimethylenediamine (L), with the formula NiLCl2-6H2O. The Schiff bases were characterized by elemental analysis, IR spectroscopy and 1H and 13C-NMR. The NiII compound was characterized by elemental analysis, IR, UV and visible spectroscopy, magnetic susceptibility and thermal analysis. A tetrahedral environment set N2Cl2 of donor atoms is proposed for NiIIRead More
Publication Year: 1989
Publication Date: 1989-04-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 1
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