Electrosynthesis of alkyl and aryloxy titanium(III) complexes; electrochemical and spectroscopic characterization

Name: Work Video:
Duration: 3 min 30 s
Description: Electrochemical or chemical reduction of mono- or dicyclopentadienyl TiIV complexes gives the corrsponding radical anions which rearrange rapidly in both cases to the corresponding neutral monocyclopentadienyl TiIII complexes; by a combination of electrochemical and e.s.r. techniques, it was possible to understand the mechanism of reduction of these TiIV complexes.
Annie Chaloyard; A. Dormond; J. Tirouflet; Nabil El Murr
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