Title: Zn(tbip) (H<sub>2</sub>tbip= 5-<i>tert</i>-Butyl Isophthalic Acid): A Highly Stable Guest-Free Microporous Metal Organic Framework with Unique Gas Separation Capability
Abstract:A novel guest-free metal organic framework (GFMMOF) is synthesized and structurally characterized. It contains one-dimensional close-packed open channels with a pore diameter of 4.5 A. It demonstrates...A novel guest-free metal organic framework (GFMMOF) is synthesized and structurally characterized. It contains one-dimensional close-packed open channels with a pore diameter of 4.5 A. It demonstrates a remarkable thermal stability, a unique ability to separate methanol from dimethyl ether or water, and is among the microporous MOFs having the highest adsorbed hydrogen density (0.054 g/cm3 at 77 K and 1 atm).Read More
Publication Year: 2006
Publication Date: 2006-03-14
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']
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Cited By Count: 426
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