Transmetalation of a nucleophilic carbene fragment: from early to late transition metals

Name: Work Video:
Duration: 3 min 30 s
Description: Early transition metal nucleophilic carbene complexes have been used as stoichiometric carbene transfer agents in a transmetalation process.
Marie Fustier‐Boutignon; Hadrien Heuclin; X.F. Le Goff; Nicolas Mézailles
{'id': 'https://openalex.org/W1999943747', 'doi': 'https://doi.org/10.1039/c2cc17934b', 'title': 'Transmetalation of a nucleophilic carbene fragment: from early to late transition metals', 'display_name': 'Transmetalation of a nucleophilic carbene fragment: from early to late transition metals', 'publication_year': 2012, 'publication_date': '2012-01-01', 'ids': {'openalex': 'https://openalex.org/W1999943747', 'doi': 'https://doi.org/10.1039/c2cc17934b', 'mag': '1999943747', 'pmid': 'https://pubmed.ncbi.nlm.nih.gov/22358183'}, 'language': 'en', 'primary_location': {'is_oa': False, 'landing_page_url': 'https://doi.org/10.1039/c2cc17934b', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S152760256', 'display_name': 'Chemical Communications', 'issn_l': '1359-7345', 'issn': ['1359-7345', '1364-548X'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320556', 'host_organization_name': 'Royal Society of Chemistry', 'host_organization_lineage': ['https://openalex.org/P4310320556'], 'host_organization_lineage_names': ['Royal Society of Chemistry'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}, 'type': 'article', 'type_crossref': 'journal-article', 'indexed_in': ['crossref', 'pubmed'], 'open_access': {'is_oa': False, 'oa_status': 'closed', 'oa_url': None, 'any_repository_has_fulltext': False}, 'authorships': [{'author_position': 'first', 'author': {'id': 'https://openalex.org/A5033567540', 'display_name': 'Marie Fustier‐Boutignon', 'orcid': 'https://orcid.org/0000-0002-1180-3680'}, 'institutions': [{'id': 'https://openalex.org/I142476485', 'display_name': 'École Polytechnique', 'ror': 'https://ror.org/05hy3tk52', 'country_code': 'FR', 'type': 'education', 'lineage': ['https://openalex.org/I142476485', 'https://openalex.org/I4210145102']}, {'id': 'https://openalex.org/I1294671590', 'display_name': 'Centre National de la Recherche Scientifique', 'ror': 'https://ror.org/02feahw73', 'country_code': 'FR', 'type': 'government', 'lineage': ['https://openalex.org/I1294671590']}], 'countries': ['FR'], 'is_corresponding': False, 'raw_author_name': 'Marie Fustier-Boutignon', 'raw_affiliation_strings': ['Laboratoire Hétéroéléments et Coordination, Ecole Polytechnique CNRS, Palaiseau, France.'], 'affiliations': [{'raw_affiliation_string': 'Laboratoire Hétéroéléments et Coordination, Ecole Polytechnique CNRS, Palaiseau, France.', 'institution_ids': ['https://openalex.org/I142476485', 'https://openalex.org/I1294671590']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5053283832', 'display_name': 'Hadrien Heuclin', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I142476485', 'display_name': 'École Polytechnique', 'ror': 'https://ror.org/05hy3tk52', 'country_code': 'FR', 'type': 'education', 'lineage': ['https://openalex.org/I142476485', 'https://openalex.org/I4210145102']}, {'id': 'https://openalex.org/I1294671590', 'display_name': 'Centre National de la Recherche Scientifique', 'ror': 'https://ror.org/02feahw73', 'country_code': 'FR', 'type': 'government', 'lineage': ['https://openalex.org/I1294671590']}], 'countries': ['FR'], 'is_corresponding': False, 'raw_author_name': 'Hadrien Heuclin', 'raw_affiliation_strings': ['Laboratoire Hétéroéléments et Coordination, Ecole Polytechnique CNRS, Palaiseau, France.'], 'affiliations': [{'raw_affiliation_string': 'Laboratoire Hétéroéléments et Coordination, Ecole Polytechnique CNRS, Palaiseau, France.', 'institution_ids': ['https://openalex.org/I142476485', 'https://openalex.org/I1294671590']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5102718079', 'display_name': 'X.F. Le Goff', 'orcid': 'https://orcid.org/0000-0002-5041-0468'}, 'institutions': [{'id': 'https://openalex.org/I1294671590', 'display_name': 'Centre National de la Recherche Scientifique', 'ror': 'https://ror.org/02feahw73', 'country_code': 'FR', 'type': 'government', 'lineage': ['https://openalex.org/I1294671590']}, {'id': 'https://openalex.org/I142476485', 'display_name': 'École Polytechnique', 'ror': 'https://ror.org/05hy3tk52', 'country_code': 'FR', 'type': 'education', 'lineage': ['https://openalex.org/I142476485', 'https://openalex.org/I4210145102']}], 'countries': ['FR'], 'is_corresponding': False, 'raw_author_name': 'Xavier Frédéric Le Goff', 'raw_affiliation_strings': ['Laboratoire Hétéroéléments et Coordination, Ecole Polytechnique CNRS, Palaiseau, France.'], 'affiliations': [{'raw_affiliation_string': 'Laboratoire Hétéroéléments et Coordination, Ecole Polytechnique CNRS, Palaiseau, France.', 'institution_ids': ['https://openalex.org/I1294671590', 'https://openalex.org/I142476485']}]}, {'author_position': 'last', 'author': {'id': 'https://openalex.org/A5042200173', 'display_name': 'Nicolas Mézailles', 'orcid': 'https://orcid.org/0000-0001-8735-6285'}, 'institutions': [{'id': 'https://openalex.org/I142476485', 'display_name': 'École Polytechnique', 'ror': 'https://ror.org/05hy3tk52', 'country_code': 'FR', 'type': 'education', 'lineage': ['https://openalex.org/I142476485', 'https://openalex.org/I4210145102']}, {'id': 'https://openalex.org/I1294671590', 'display_name': 'Centre National de la Recherche Scientifique', 'ror': 'https://ror.org/02feahw73', 'country_code': 'FR', 'type': 'government', 'lineage': ['https://openalex.org/I1294671590']}], 'countries': ['FR'], 'is_corresponding': False, 'raw_author_name': 'Nicolas Mézailles', 'raw_affiliation_strings': ['Laboratoire Hétéroéléments et Coordination, Ecole Polytechnique CNRS, Palaiseau, France.'], 'affiliations': [{'raw_affiliation_string': 'Laboratoire Hétéroéléments et Coordination, Ecole Polytechnique CNRS, Palaiseau, France.', 'institution_ids': ['https://openalex.org/I142476485', 'https://openalex.org/I1294671590']}]}], 'institution_assertions': [], 'countries_distinct_count': 1, 'institutions_distinct_count': 2, 'corresponding_author_ids': [], 'corresponding_institution_ids': [], 'apc_list': None, 'apc_paid': None, 'fwci': 2.374, 'has_fulltext': True, 'fulltext_origin': 'ngrams', 'cited_by_count': 34, 'citation_normalized_percentile': {'value': 0.917873, 'is_in_top_1_percent': False, 'is_in_top_10_percent': True}, 'cited_by_percentile_year': {'min': 93, 'max': 94}, 'biblio': {'volume': '48', 'issue': '27', 'first_page': '3306', 'last_page': '3306'}, 'is_retracted': False, 'is_paratext': False, 'primary_topic': {'id': 'https://openalex.org/T11790', 'display_name': 'N-Heterocyclic Carbenes in Organic and Inorganic Chemistry', 'score': 0.9999, 'subfield': {'id': 'https://openalex.org/subfields/1605', 'display_name': 'Organic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, 'topics': [{'id': 'https://openalex.org/T11790', 'display_name': 'N-Heterocyclic Carbenes in Organic and Inorganic Chemistry', 'score': 0.9999, 'subfield': {'id': 'https://openalex.org/subfields/1605', 'display_name': 'Organic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T10548', 'display_name': 'Catalytic Cross-Coupling Reactions', 'score': 0.9998, 'subfield': {'id': 'https://openalex.org/subfields/1605', 'display_name': 'Organic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T10092', 'display_name': 'Organometallic Complex Synthesis and Catalysis', 'score': 0.9994, 'subfield': {'id': 'https://openalex.org/subfields/1605', 'display_name': 'Organic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}], 'keywords': [{'id': 'https://openalex.org/keywords/transmetalation', 'display_name': 'Transmetalation', 'score': 0.99049264}, {'id': 'https://openalex.org/keywords/stoichiometry', 'display_name': 'Stoichiometry', 'score': 0.49892545}], 'concepts': [{'id': 'https://openalex.org/C142653250', 'wikidata': 'https://www.wikidata.org/wiki/Q900742', 'display_name': 'Transmetalation', 'level': 3, 'score': 0.99049264}, {'id': 'https://openalex.org/C2777164566', 'wikidata': 'https://www.wikidata.org/wiki/Q419257', 'display_name': 'Carbene', 'level': 3, 'score': 0.9713652}, {'id': 'https://openalex.org/C178907741', 'wikidata': 'https://www.wikidata.org/wiki/Q745930', 'display_name': 'Nucleophile', 'level': 3, 'score': 0.6972664}, {'id': 'https://openalex.org/C106773901', 'wikidata': 'https://www.wikidata.org/wiki/Q19588', 'display_name': 'Transition metal', 'level': 3, 'score': 0.6027731}, {'id': 'https://openalex.org/C86914705', 'wikidata': 'https://www.wikidata.org/wiki/Q414293', 'display_name': 'Transition metal carbene complex', 'level': 4, 'score': 0.5863232}, {'id': 'https://openalex.org/C185592680', 'wikidata': 'https://www.wikidata.org/wiki/Q2329', 'display_name': 'Chemistry', 'level': 0, 'score': 0.5508136}, {'id': 'https://openalex.org/C144082473', 'wikidata': 'https://www.wikidata.org/wiki/Q213185', 'display_name': 'Stoichiometry', 'level': 2, 'score': 0.49892545}, {'id': 'https://openalex.org/C75473681', 'wikidata': 'https://www.wikidata.org/wiki/Q188651', 'display_name': 'Photochemistry', 'level': 1, 'score': 0.35593712}, {'id': 'https://openalex.org/C178790620', 'wikidata': 'https://www.wikidata.org/wiki/Q11351', 'display_name': 'Organic chemistry', 'level': 1, 'score': 0.25435412}, {'id': 'https://openalex.org/C161790260', 'wikidata': 'https://www.wikidata.org/wiki/Q82264', 'display_name': 'Catalysis', 'level': 2, 'score': 0.11258736}], 'mesh': [], 'locations_count': 4, 'locations': [{'is_oa': False, 'landing_page_url': 'https://doi.org/10.1039/c2cc17934b', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S152760256', 'display_name': 'Chemical Communications', 'issn_l': '1359-7345', 'issn': ['1359-7345', '1364-548X'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320556', 'host_organization_name': 'Royal Society of Chemistry', 'host_organization_lineage': ['https://openalex.org/P4310320556'], 'host_organization_lineage_names': ['Royal Society of Chemistry'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}, {'is_oa': False, 'landing_page_url': 'https://hal.archives-ouvertes.fr/hal-00691848', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S4306402512', 'display_name': 'HAL (Le Centre pour la Communication Scientifique Directe)', 'issn_l': None, 'issn': None, 'is_oa': True, 'is_in_doaj': False, 'is_core': False, 'host_organization': 'https://openalex.org/I1294671590', 'host_organization_name': 'Centre National de la Recherche Scientifique', 'host_organization_lineage': ['https://openalex.org/I1294671590'], 'host_organization_lineage_names': ['Centre National de la Recherche Scientifique'], 'type': 'repository'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}, {'is_oa': False, 'landing_page_url': 'https://hal.science/hal-00691848', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S4306402512', 'display_name': 'HAL (Le Centre pour la Communication Scientifique Directe)', 'issn_l': None, 'issn': None, 'is_oa': True, 'is_in_doaj': False, 'is_core': False, 'host_organization': 'https://openalex.org/I1294671590', 'host_organization_name': 'Centre National de la Recherche Scientifique', 'host_organization_lineage': ['https://openalex.org/I1294671590'], 'host_organization_lineage_names': ['Centre National de la Recherche Scientifique'], 'type': 'repository'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}, {'is_oa': False, 'landing_page_url': 'https://pubmed.ncbi.nlm.nih.gov/22358183', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S4306525036', 'display_name': 'PubMed', 'issn_l': None, 'issn': None, 'is_oa': False, 'is_in_doaj': False, 'is_core': False, 'host_organization': 'https://openalex.org/I1299303238', 'host_organization_name': 'National Institutes of Health', 'host_organization_lineage': ['https://openalex.org/I1299303238'], 'host_organization_lineage_names': ['National Institutes of Health'], 'type': 'repository'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}], 'best_oa_location': None, 'sustainable_development_goals': [], 'grants': [], 'datasets': ['https://openalex.org/W4398083298', 'https://openalex.org/W4398123634'], 'versions': [], 'referenced_works_count': 43, 'referenced_works': ['https://openalex.org/W1970023260', 'https://openalex.org/W1971643970', 'https://openalex.org/W1978188241', 'https://openalex.org/W1984150125', 'https://openalex.org/W1986466156', 'https://openalex.org/W1992978006', 'https://openalex.org/W1994890915', 'https://openalex.org/W1995629903', 'https://openalex.org/W2000518158', 'https://openalex.org/W2001511459', 'https://openalex.org/W2007302041', 'https://openalex.org/W2016304228', 'https://openalex.org/W2019176142', 'https://openalex.org/W2019913856', 'https://openalex.org/W2022144021', 'https://openalex.org/W2024863575', 'https://openalex.org/W2026885884', 'https://openalex.org/W2028194121', 'https://openalex.org/W2030699693', 'https://openalex.org/W2031829063', 'https://openalex.org/W2042253155', 'https://openalex.org/W2042396463', 'https://openalex.org/W2042483575', 'https://openalex.org/W2043919887', 'https://openalex.org/W2054433914', 'https://openalex.org/W2056495580', 'https://openalex.org/W2057732674', 'https://openalex.org/W2059644602', 'https://openalex.org/W2065169748', 'https://openalex.org/W2074914044', 'https://openalex.org/W2076094680', 'https://openalex.org/W2085615658', 'https://openalex.org/W2089412884', 'https://openalex.org/W2094445166', 'https://openalex.org/W2116910781', 'https://openalex.org/W2118126257', 'https://openalex.org/W2122253595', 'https://openalex.org/W2131382008', 'https://openalex.org/W2150002066', 'https://openalex.org/W2163731546', 'https://openalex.org/W2316016196', 'https://openalex.org/W2320715933', 'https://openalex.org/W2953005242'], 'related_works': ['https://openalex.org/W3182896105', 'https://openalex.org/W2953344628', 'https://openalex.org/W2953140053', 'https://openalex.org/W2949197892', 'https://openalex.org/W2769155976', 'https://openalex.org/W2497556154', 'https://openalex.org/W2190744179', 'https://openalex.org/W2116910781', 'https://openalex.org/W2054687606', 'https://openalex.org/W1991329575'], 'abstract_inverted_index': {'Early': [0], 'transition': [1], 'metal': [2], 'nucleophilic': [3], 'carbene': [4, 11], 'complexes': [5], 'have': [6], 'been': [7], 'used': [8], 'as': [9], 'stoichiometric': [10], 'transfer': [12], 'agents': [13], 'in': [14], 'a': [15], 'transmetalation': [16], 'process.': [17]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W1999943747', 'counts_by_year': [{'year': 2024, 'cited_by_count': 2}, {'year': 2023, 'cited_by_count': 2}, {'year': 2021, 'cited_by_count': 3}, {'year': 2020, 'cited_by_count': 2}, {'year': 2019, 'cited_by_count': 1}, {'year': 2018, 'cited_by_count': 1}, {'year': 2017, 'cited_by_count': 2}, {'year': 2016, 'cited_by_count': 3}, {'year': 2015, 'cited_by_count': 4}, {'year': 2014, 'cited_by_count': 5}, {'year': 2013, 'cited_by_count': 7}, {'year': 2012, 'cited_by_count': 1}], 'updated_date': '2024-12-14T16:25:00.761745', 'created_date': '2016-06-24'}
Publication Information

Basic Information

Access and Citation

AI Researcher Chatbot

Primary Location

Authors

Topics

Keywords

Related Works
