Title: Reversible Isomerization of the Dinuclear Complex [(η<sup>6</sup>‐<i>p</i>‐cymene)RuCl(μ‐pz)<sub>2</sub> Ir(CO)<sub>2</sub>] with Formation of a Ruthenium‐Iridium Bond
Abstract:The doubly-bridged Ru-Ir pyrazolyl complex 1 easily isomerizes under very mild conditions with reversible metal-metal bond formation accompanied by halide migration to give 2. Such isomerizations, whi...The doubly-bridged Ru-Ir pyrazolyl complex 1 easily isomerizes under very mild conditions with reversible metal-metal bond formation accompanied by halide migration to give 2. Such isomerizations, which take place without addition or removal of ligands, are of central importance in connection with the catalytic activity of dinuclear metal complexes. L = p-cymene, NN symbolizes the NN unit of the pyrazolyl ligand.Read More
Publication Year: 1991
Publication Date: 1991-09-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 28
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