Get quick answers to your questions about the article from our AI researcher chatbot
{'id': 'https://openalex.org/W1994773831', 'doi': 'https://doi.org/10.1002/1099-0682(200007)2000:7<1581::aid-ejic1581>3.0.co;2-2', 'title': 'Synthesis and Properties of Dinuclear Complexes with a Photochromic Bridge: An Intervalence Electron Transfer Switching “On” and “Off”', 'display_name': 'Synthesis and Properties of Dinuclear Complexes with a Photochromic Bridge: An Intervalence Electron Transfer Switching “On” and “Off”', 'publication_year': 2000, 'publication_date': '2000-07-01', 'ids': {'openalex': 'https://openalex.org/W1994773831', 'doi': 'https://doi.org/10.1002/1099-0682(200007)2000:7<1581::aid-ejic1581>3.0.co;2-2', 'mag': '1994773831'}, 'language': 'en', 'primary_location': {'is_oa': False, 'landing_page_url': 'https://doi.org/10.1002/1099-0682(200007)2000:7<1581::aid-ejic1581>3.0.co;2-2', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S16435181', 'display_name': 'European Journal of Inorganic Chemistry', 'issn_l': '1434-1948', 'issn': ['1434-1948', '1099-0682'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320595', 'host_organization_name': 'Wiley', 'host_organization_lineage': ['https://openalex.org/P4310320595'], 'host_organization_lineage_names': ['Wiley'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}, 'type': 'article', 'type_crossref': 'journal-article', 'indexed_in': ['crossref'], 'open_access': {'is_oa': False, 'oa_status': 'closed', 'oa_url': None, 'any_repository_has_fulltext': False}, 'authorships': [{'author_position': 'first', 'author': {'id': 'https://openalex.org/A5016227783', 'display_name': 'Sandrine Fraysse', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I4210135147', 'display_name': 'Centre d’Élaboration de Matériaux et d’Études Structurales', 'ror': 'https://ror.org/03kwnqq69', 'country_code': 'FR', 'type': 'facility', 'lineage': ['https://openalex.org/I1294671590', 'https://openalex.org/I134560555', 'https://openalex.org/I196454796', 'https://openalex.org/I4210098836', 'https://openalex.org/I4210135147', 'https://openalex.org/I4388446414']}, {'id': 'https://openalex.org/I1294671590', 'display_name': 'Centre National de la Recherche Scientifique', 'ror': 'https://ror.org/02feahw73', 'country_code': 'FR', 'type': 'government', 'lineage': ['https://openalex.org/I1294671590']}], 'countries': ['FR'], 'is_corresponding': False, 'raw_author_name': 'Sandrine Fraysse', 'raw_affiliation_strings': ['Centre d’Elaboration de Matériaux et d’Etudes Structurales, CNRS, 29 rue Jeanne Marvig, 31055 Toulouse Cedex, France, Fax: (internat.) + 33-5/62257999'], 'affiliations': [{'raw_affiliation_string': 'Centre d’Elaboration de Matériaux et d’Etudes Structurales, CNRS, 29 rue Jeanne Marvig, 31055 Toulouse Cedex, France, Fax: (internat.) + 33-5/62257999', 'institution_ids': ['https://openalex.org/I4210135147', 'https://openalex.org/I1294671590']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5086523996', 'display_name': 'Christophe Coudret', 'orcid': 'https://orcid.org/0000-0001-7334-5112'}, 'institutions': [{'id': 'https://openalex.org/I4210135147', 'display_name': 'Centre d’Élaboration de Matériaux et d’Études Structurales', 'ror': 'https://ror.org/03kwnqq69', 'country_code': 'FR', 'type': 'facility', 'lineage': ['https://openalex.org/I1294671590', 'https://openalex.org/I134560555', 'https://openalex.org/I196454796', 'https://openalex.org/I4210098836', 'https://openalex.org/I4210135147', 'https://openalex.org/I4388446414']}, {'id': 'https://openalex.org/I1294671590', 'display_name': 'Centre National de la Recherche Scientifique', 'ror': 'https://ror.org/02feahw73', 'country_code': 'FR', 'type': 'government', 'lineage': ['https://openalex.org/I1294671590']}], 'countries': ['FR'], 'is_corresponding': False, 'raw_author_name': 'Christophe Coudret', 'raw_affiliation_strings': ['Centre d’Elaboration de Matériaux et d’Etudes Structurales, CNRS, 29 rue Jeanne Marvig, 31055 Toulouse Cedex, France, Fax: (internat.) + 33-5/62257999'], 'affiliations': [{'raw_affiliation_string': 'Centre d’Elaboration de Matériaux et d’Etudes Structurales, CNRS, 29 rue Jeanne Marvig, 31055 Toulouse Cedex, France, Fax: (internat.) + 33-5/62257999', 'institution_ids': ['https://openalex.org/I4210135147', 'https://openalex.org/I1294671590']}]}, {'author_position': 'last', 'author': {'id': 'https://openalex.org/A5021657621', 'display_name': 'Jean‐Pierre Launay', 'orcid': 'https://orcid.org/0000-0002-2242-0175'}, 'institutions': [{'id': 'https://openalex.org/I4210135147', 'display_name': 'Centre d’Élaboration de Matériaux et d’Études Structurales', 'ror': 'https://ror.org/03kwnqq69', 'country_code': 'FR', 'type': 'facility', 'lineage': ['https://openalex.org/I1294671590', 'https://openalex.org/I134560555', 'https://openalex.org/I196454796', 'https://openalex.org/I4210098836', 'https://openalex.org/I4210135147', 'https://openalex.org/I4388446414']}, {'id': 'https://openalex.org/I1294671590', 'display_name': 'Centre National de la Recherche Scientifique', 'ror': 'https://ror.org/02feahw73', 'country_code': 'FR', 'type': 'government', 'lineage': ['https://openalex.org/I1294671590']}], 'countries': ['FR'], 'is_corresponding': False, 'raw_author_name': 'Jean-Pierre Launay', 'raw_affiliation_strings': ['Centre d’Elaboration de Matériaux et d’Etudes Structurales, CNRS, 29 rue Jeanne Marvig, 31055 Toulouse Cedex, France, Fax: (internat.) + 33-5/62257999'], 'affiliations': [{'raw_affiliation_string': 'Centre d’Elaboration de Matériaux et d’Etudes Structurales, CNRS, 29 rue Jeanne Marvig, 31055 Toulouse Cedex, France, Fax: (internat.) + 33-5/62257999', 'institution_ids': ['https://openalex.org/I4210135147', 'https://openalex.org/I1294671590']}]}], 'institution_assertions': [], 'countries_distinct_count': 1, 'institutions_distinct_count': 2, 'corresponding_author_ids': [], 'corresponding_institution_ids': [], 'apc_list': {'value': 3860, 'currency': 'USD', 'value_usd': 3860, 'provenance': 'doaj'}, 'apc_paid': None, 'fwci': 4.277, 'has_fulltext': True, 'fulltext_origin': 'ngrams', 'cited_by_count': 206, 'citation_normalized_percentile': {'value': 0.965631, 'is_in_top_1_percent': False, 'is_in_top_10_percent': True}, 'cited_by_percentile_year': {'min': 98, 'max': 99}, 'biblio': {'volume': '2000', 'issue': '7', 'first_page': '1581', 'last_page': '1590'}, 'is_retracted': False, 'is_paratext': False, 'primary_topic': {'id': 'https://openalex.org/T11708', 'display_name': 'Photochromic and Fluorescence Chemistry', 'score': 1.0, 'subfield': {'id': 'https://openalex.org/subfields/2505', 'display_name': 'Materials Chemistry'}, 'field': {'id': 'https://openalex.org/fields/25', 'display_name': 'Materials Science'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, 'topics': [{'id': 'https://openalex.org/T11708', 'display_name': 'Photochromic and Fluorescence Chemistry', 'score': 1.0, 'subfield': {'id': 'https://openalex.org/subfields/2505', 'display_name': 'Materials Chemistry'}, 'field': {'id': 'https://openalex.org/fields/25', 'display_name': 'Materials Science'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T10903', 'display_name': 'Porphyrin and Phthalocyanine Chemistry', 'score': 0.9988, 'subfield': {'id': 'https://openalex.org/subfields/2505', 'display_name': 'Materials Chemistry'}, 'field': {'id': 'https://openalex.org/fields/25', 'display_name': 'Materials Science'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T10701', 'display_name': 'Radical Photochemical Reactions', 'score': 0.9964, 'subfield': {'id': 'https://openalex.org/subfields/1605', 'display_name': 'Organic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}], 'keywords': [{'id': 'https://openalex.org/keywords/quadricyclane', 'display_name': 'Quadricyclane', 'score': 0.78786826}, {'id': 'https://openalex.org/keywords/comproportionation', 'display_name': 'Comproportionation', 'score': 0.65036905}, {'id': 'https://openalex.org/keywords/trifluoromethanesulfonate', 'display_name': 'Trifluoromethanesulfonate', 'score': 0.6322498}, {'id': 'https://openalex.org/keywords/photoswitch', 'display_name': 'Photoswitch', 'score': 0.5294506}, {'id': 'https://openalex.org/keywords/photostationary-state', 'display_name': 'Photostationary state', 'score': 0.45580247}, {'id': 'https://openalex.org/keywords/bipyridine', 'display_name': 'Bipyridine', 'score': 0.43375754}], 'concepts': [{'id': 'https://openalex.org/C185592680', 'wikidata': 'https://www.wikidata.org/wiki/Q2329', 'display_name': 'Chemistry', 'level': 0, 'score': 0.93002367}, {'id': 'https://openalex.org/C555196967', 'wikidata': 'https://www.wikidata.org/wiki/Q1086', 'display_name': 'Ruthenium', 'level': 3, 'score': 0.899739}, {'id': 'https://openalex.org/C2780669175', 'wikidata': 'https://www.wikidata.org/wiki/Q726795', 'display_name': 'Norbornadiene', 'level': 3, 'score': 0.898923}, {'id': 'https://openalex.org/C81180622', 'wikidata': 'https://www.wikidata.org/wiki/Q899324', 'display_name': 'Photochromism', 'level': 2, 'score': 0.8731055}, {'id': 'https://openalex.org/C2781113223', 'wikidata': 'https://www.wikidata.org/wiki/Q2913270', 'display_name': 'Quadricyclane', 'level': 4, 'score': 0.78786826}, {'id': 'https://openalex.org/C75473681', 'wikidata': 'https://www.wikidata.org/wiki/Q188651', 'display_name': 'Photochemistry', 'level': 1, 'score': 0.69043905}, {'id': 'https://openalex.org/C85311670', 'wikidata': 'https://www.wikidata.org/wiki/Q2349383', 'display_name': 'Photoisomerization', 'level': 4, 'score': 0.6571376}, {'id': 'https://openalex.org/C164397293', 'wikidata': 'https://www.wikidata.org/wiki/Q584415', 'display_name': 'Comproportionation', 'level': 4, 'score': 0.65036905}, {'id': 'https://openalex.org/C21774173', 'wikidata': 'https://www.wikidata.org/wiki/Q2462024', 'display_name': 'Trifluoromethanesulfonate', 'level': 3, 'score': 0.6322498}, {'id': 'https://openalex.org/C75079739', 'wikidata': 'https://www.wikidata.org/wiki/Q1571801', 'display_name': 'Intramolecular force', 'level': 2, 'score': 0.6127171}, {'id': 'https://openalex.org/C2776663404', 'wikidata': 'https://www.wikidata.org/wiki/Q5479379', 'display_name': 'Photoswitch', 'level': 2, 'score': 0.5294506}, {'id': 'https://openalex.org/C123669783', 'wikidata': 'https://www.wikidata.org/wiki/Q902898', 'display_name': 'Electron transfer', 'level': 2, 'score': 0.48837227}, {'id': 'https://openalex.org/C86048148', 'wikidata': 'https://www.wikidata.org/wiki/Q7187910', 'display_name': 'Photostationary state', 'level': 5, 'score': 0.45580247}, {'id': 'https://openalex.org/C106773901', 'wikidata': 'https://www.wikidata.org/wiki/Q19588', 'display_name': 'Transition metal', 'level': 3, 'score': 0.443141}, {'id': 'https://openalex.org/C2779336533', 'wikidata': 'https://www.wikidata.org/wiki/Q413658', 'display_name': 'Bipyridine', 'level': 3, 'score': 0.43375754}, {'id': 'https://openalex.org/C101643646', 'wikidata': 'https://www.wikidata.org/wiki/Q899105', 'display_name': 'Electrochromism', 'level': 3, 'score': 0.43317765}, {'id': 'https://openalex.org/C8010536', 'wikidata': 'https://www.wikidata.org/wiki/Q160398', 'display_name': 'Crystallography', 'level': 1, 'score': 0.2737342}, {'id': 'https://openalex.org/C71240020', 'wikidata': 'https://www.wikidata.org/wiki/Q186011', 'display_name': 'Stereochemistry', 'level': 1, 'score': 0.23253545}, {'id': 'https://openalex.org/C161790260', 'wikidata': 'https://www.wikidata.org/wiki/Q82264', 'display_name': 'Catalysis', 'level': 2, 'score': 0.202559}, {'id': 'https://openalex.org/C147789679', 'wikidata': 'https://www.wikidata.org/wiki/Q11372', 'display_name': 'Physical chemistry', 'level': 1, 'score': 0.16682515}, {'id': 'https://openalex.org/C178790620', 'wikidata': 'https://www.wikidata.org/wiki/Q11351', 'display_name': 'Organic chemistry', 'level': 1, 'score': 0.12733784}, {'id': 'https://openalex.org/C115624301', 'wikidata': 'https://www.wikidata.org/wiki/Q895901', 'display_name': 'Crystal structure', 'level': 2, 'score': 0.11733493}, {'id': 'https://openalex.org/C126661725', 'wikidata': 'https://www.wikidata.org/wiki/Q903420', 'display_name': 'Isomerization', 'level': 3, 'score': 0.1165643}, {'id': 'https://openalex.org/C17525397', 'wikidata': 'https://www.wikidata.org/wiki/Q176140', 'display_name': 'Electrode', 'level': 2, 'score': 0.0}, {'id': 'https://openalex.org/C52859227', 'wikidata': 'https://www.wikidata.org/wiki/Q7877', 'display_name': 'Electrochemistry', 'level': 3, 'score': 0.0}], 'mesh': [], 'locations_count': 1, 'locations': [{'is_oa': False, 'landing_page_url': 'https://doi.org/10.1002/1099-0682(200007)2000:7<1581::aid-ejic1581>3.0.co;2-2', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S16435181', 'display_name': 'European Journal of Inorganic Chemistry', 'issn_l': '1434-1948', 'issn': ['1434-1948', '1099-0682'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320595', 'host_organization_name': 'Wiley', 'host_organization_lineage': ['https://openalex.org/P4310320595'], 'host_organization_lineage_names': ['Wiley'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}], 'best_oa_location': None, 'sustainable_development_goals': [{'display_name': 'Clean water and sanitation', 'id': 'https://metadata.un.org/sdg/6', 'score': 0.62}], 'grants': [], 'datasets': ['https://openalex.org/W4397212141'], 'versions': [], 'referenced_works_count': 31, 'referenced_works': ['https://openalex.org/W1966377407', 'https://openalex.org/W1973833581', 'https://openalex.org/W1974764136', 'https://openalex.org/W1988213097', 'https://openalex.org/W1990291555', 'https://openalex.org/W1990678626', 'https://openalex.org/W2004875810', 'https://openalex.org/W2005728565', 'https://openalex.org/W2005734998', 'https://openalex.org/W2007192948', 'https://openalex.org/W2013985799', 'https://openalex.org/W2016667630', 'https://openalex.org/W2023541421', 'https://openalex.org/W2024536147', 'https://openalex.org/W2025535556', 'https://openalex.org/W2030971064', 'https://openalex.org/W2039090269', 'https://openalex.org/W2047351256', 'https://openalex.org/W2051412139', 'https://openalex.org/W2054412489', 'https://openalex.org/W2088303431', 'https://openalex.org/W2089327344', 'https://openalex.org/W2091805175', 'https://openalex.org/W2118991015', 'https://openalex.org/W2158957899', 'https://openalex.org/W2949361784', 'https://openalex.org/W2949786048', 'https://openalex.org/W2950629420', 'https://openalex.org/W2952544185', 'https://openalex.org/W4247172804', 'https://openalex.org/W4250456190'], 'related_works': ['https://openalex.org/W4390587143', 'https://openalex.org/W4241697564', 'https://openalex.org/W3159480049', 'https://openalex.org/W3017047827', 'https://openalex.org/W2955821059', 'https://openalex.org/W2919301902', 'https://openalex.org/W2898064755', 'https://openalex.org/W2594618489', 'https://openalex.org/W2085023647', 'https://openalex.org/W1994773831'], 'abstract_inverted_index': {'European': [0], 'Journal': [1], 'of': [2, 15, 235, 245, 258, 269, 304, 322, 339, 356, 404, 411, 443, 462, 479, 1058, 1113, 1127, 1157, 1178, 1181, 1268, 1280, 1397, 1404, 1410, 1435, 1441, 1450, 1471, 1477, 1492, 1588, 1617, 1635, 1737, 1773], 'Inorganic': [3], 'ChemistryVolume': [4], '2000,': [5], 'Issue': [6, 1767], '7': [7], 'p.': [8, 544], '1581-1590': [9, 1831], 'Full': [10], 'Paper': [11], 'Synthesis': [12, 987], 'and': [13, 28, 233, 237, 249, 256, 275, 317, 345, 413, 428, 488, 501, 531, 672, 1133, 1209, 1255, 1373, 1383, 1431, 1484], 'Properties': [14], 'Dinuclear': [16], 'Complexes': [17], 'with': [18, 272, 354, 449, 1318, 1412], 'a': [19, 266, 281, 1059, 1329, 1478, 1490, 1614, 1618, 1623, 1732], 'Photochromic': [20], 'Bridge:': [21], 'An': [22, 398], 'Intervalence': [23], 'Electron': [24], 'Transfer': [25], 'Switching': [26], '“On”': [27], '“Off”': [29], 'Sandrine': [30, 32, 120, 122], 'Fraysse,': [31, 121, 903, 913, 1704], 'Fraysse': [33, 123], 'Centre': [34, 65, 94, 124, 155, 184], 'd’Elaboration': [35, 66, 95, 125, 156, 185], 'de': [36, 67, 96, 126, 157, 186], 'Matériaux': [37, 68, 97, 127, 158, 187], 'et': [38, 69, 98, 128, 159, 188], 'd’Etudes': [39, 70, 99, 129, 160, 189], 'Structurales,': [40, 71, 100, 130, 161, 190], 'CNRS,': [41, 72, 101, 131, 162, 191], '29': [42, 73, 102, 132, 163, 192], 'rue': [43, 74, 103, 133, 164, 193], 'Jeanne': [44, 75, 104, 134, 165, 194], 'Marvig,': [45, 76, 105, 135, 166, 195], '31055': [46, 77, 106, 136, 167, 196], 'Toulouse': [47, 78, 107, 137, 168, 197], 'Cedex,': [48, 79, 108, 138, 169, 198], 'France,': [49, 80, 109, 139, 170, 199], 'Fax:': [50, 81, 110, 140, 171, 200], '(internat.)': [51, 82, 111, 141, 172, 201], '+': [52, 83, 112, 142, 173, 202], '33-5/62257999Search': [53, 84, 113, 143, 174, 203], 'for': [54, 85, 114, 144, 175, 204, 332, 343, 373, 408, 432, 436, 483, 1135, 1146, 1346, 1734], 'more': [55, 86, 115, 145, 176, 205, 1502], 'papers': [56, 87, 116, 146, 177, 206], 'by': [57, 88, 117, 147, 178, 207, 362, 1622, 1638, 1740], 'this': [58, 89, 118, 148, 179, 208, 270, 1269, 1369, 1451], 'authorChristophe': [59, 149], 'Coudret,': [60, 150, 605, 901, 915, 1706], 'Christophe': [61, 151], 'Coudret': [62, 152], '[email': [63, 153], 'protected]': [64, 154], 'authorJean-Pierre': [90, 180], 'Launay,': [91, 181, 580, 607, 624, 645, 704, 858, 905, 917, 1199, 1702], 'Jean-Pierre': [92, 182], 'Launay': [93, 183], 'author': [119, 209], 'First': [210], 'published:': [211], 'July': [212, 1686], '2000': [213], 'https://doi.org/10.1002/1099-0682(200007)2000:7<1581::AID-EJIC1581>3.0.CO;2-2Citations:': [214], '195AboutPDF': [215], 'ToolsRequest': [216], 'permissionExport': [217], 'citationAdd': [218], 'to': [219, 241, 264, 310, 330, 336, 393, 422, 467, 1110, 1150, 1165, 1321, 1445], 'favoritesTrack': [220], 'citation': [221], 'ShareShare': [222], 'Give': [223], 'accessShare': [224, 227], 'full': [225], 'text': [226], 'full-text': [228, 243, 267], 'accessPlease': [229], 'review': [230], 'our': [231], 'Terms': [232, 255], 'Conditions': [234, 257], 'Use': [236], 'check': [238], 'box': [239], 'below': [240, 263], 'share': [242, 265], 'version': [244, 268], 'article.I': [246], 'have': [247], 'read': [248], 'accept': [250], 'the': [251, 261, 301, 305, 312, 340, 350, 357, 381, 385, 394, 401, 409, 444, 454, 459, 463, 1111, 1114, 1121, 1138, 1155, 1158, 1179, 1182, 1189, 1207, 1244, 1259, 1266, 1323, 1335, 1395, 1398, 1408, 1413, 1433, 1438, 1469, 1475, 1487, 1501, 1506, 1630], 'Wiley': [252], 'Online': [253], 'Library': [254], 'UseShareable': [259], 'LinkUse': [260], 'link': [262], 'article': [271], 'your': [273], 'friends': [274], 'colleagues.': [276], 'Learn': [277], 'more.Copy': [278], 'URL': [279], 'Share': [280], 'linkShare': [282], 'onEmailFacebookTwitterLinkedInRedditWechat': [283], 'Abstract': [284], 'Two': [285, 320], 'cyclometallated': [286], 'Ru(bpy)2(pp)': [287], 'units': [288], '(bpy': [289], '=': [290, 293, 1283], '2,2′-bipyridine;': [291], 'pp': [292], '2-phenylpyridine)': [294], 'were': [295, 325, 1185], 'grafted': [296], 'via': [297], 'ethynyl': [298], 'spacers': [299], 'onto': [300], 'photochromic': [302], 'cores': [303], 'norbornadiene': [306], 'or': [307, 441, 1118], 'dithienylethene': [308, 341], 'families,': [309], 'give': [311, 1322], 'bimetallic': [313], 'ruthenium(II)': [314, 427], 'complexes': [315, 1122], '1': [316, 376, 1290], '2a,': [318], 'respectively.': [319], 'aspects': [321, 1261], 'these': [323, 416], 'compounds': [324], 'studied:': [326], '(i)': [327, 1394], 'photoisomerization': [328], '(norbornadiene': [329], 'quadricyclane': [331, 382], '1,': [333, 374, 671, 791, 812], 'open': [334, 1356], 'form': [335, 338, 396, 465, 1357, 1362], 'closed': [337, 395, 464, 1361], 'core': [342], '2a),': [344], '(ii)': [346, 1407], 'intervalence': [347, 419, 445, 1442], 'transitions': [348], 'in': [349, 527, 1169, 1265, 1308, 1333, 1349, 1376, 1379, 1386, 1402, 1437, 1496, 1626, 1629, 1711], 'mixed-valence': [351], 'ruthenium(II−III)': [352], 'state,': [353], 'determination': [355], 'metal−metal': [358, 366], 'electronic': [359, 367], 'coupling': [360, 368], '(Vab)': [361], 'Hush’s': [363], 'equation.': [364], 'Moderate': [365], '(0.068': [369], 'eV)': [370], 'was': [371, 406, 430, 1068, 1593], 'found': [372], 'but': [375, 434], 'cannot': [377], 'be': [378, 390, 1151, 1163, 1166], 'isomerized': [379], 'into': [380, 1500], 'form.': [383], 'On': [384], 'other': [386], 'hand,': [387], '2a': [388, 412], 'can': [389, 1162], 'reversibly': [391], 'photoisomerized': [392], '2b.': [397, 414], 'iodine(III)': [399], 'reagent,': [400], 'triflate': [402], 'salt': [403], 'bis(pyridyl)phenyliodonium,': [405], 'used': [407], 'oxidation': [410, 1302, 1592, 1616], 'During': [415], 'oxidations,': [417], 'an': [418, 477, 1063], 'band': [420], 'due': [421], 'intramolecular': [423], 'electron': [424, 1640], 'transfer': [425], 'between': [426], 'ruthenium(III)': [429], 'detected': [431], '2b,': [433], 'not': [435, 1263], '2a.': [437, 1136], 'This': [438], 'switching': [439], '“on”': [440], '“off”': [442], 'transition': [446, 1414], 'is': [447, 1338, 1385, 1453, 1464, 1468, 1474, 1481, 1486, 1494, 1508], 'rationalized': [448], 'extended': [450], 'Hückel': [451], 'calculations.': [452], 'Finally,': [453], 'molecular': [455, 480], 'orbital': [456], 'calculation': [457], 'explains': [458], 'observed': [460], 'tendency': [461], '2b': [466], 'reopen': [468], 'upon': [469, 1316, 1591], 'oxidation.': [470], 'References': [471], '[1]': [472], 'Google': [473, 505, 520, 547, 571, 574, 599, 618, 639, 661, 675, 695, 714, 754, 757, 776, 794, 815, 833, 847, 869, 898, 910, 923, 935, 951, 964, 979, 990, 1005, 1024, 1038, 1053, 1080, 1094, 1107, 1271, 1366, 1514, 1536, 1567, 1583, 1657, 1671, 1680, 1699, 1713, 1749, 1777, 1790, 1800, 1824], 'Scholar': [474, 506, 521, 548, 572, 575, 600, 619, 640, 662, 676, 696, 715, 755, 758, 777, 795, 816, 834, 848, 870, 899, 911, 924, 936, 952, 965, 980, 991, 1006, 1025, 1039, 1054, 1081, 1095, 1108, 1272, 1367, 1515, 1537, 1568, 1584, 1658, 1672, 1681, 1700, 1714, 1750, 1778, 1791, 1801, 1825], '[1a]': [475], 'For': [476, 1328, 1632], 'overview': [478], 'electronics': [481], 'see,': [482], 'instance:': [484], 'Molecular': [485, 528], 'Electronics:': [486, 529], 'Science': [487, 530], 'Technology': [489, 532], '(Eds.:': [490, 533, 940], 'A.': [491, 523, 534, 558, 610, 701, 882, 968, 983, 1194, 1225, 1230, 1721, 1812], 'Aviram,': [492, 535], 'M.': [493, 536, 581, 625, 718, 726, 732, 741, 837, 874, 876, 994, 1015, 1070, 1573, 1691, 1723, 1728, 1815], 'Ratner),': [494, 537], 'Annals': [495, 538], 'NY': [496, 539], 'Acad.': [497, 540], 'Sci.': [498, 541], '1998,': [499, 542, 595, 908, 920, 948, 1534, 1551, 1564], '852,': [500, 543], 'references': [502, 673, 1256], 'therein.': [503, 674, 1257], '−': [504, 519, 546, 598, 617, 638, 660, 775, 793, 814, 832, 1731], '[1b]': [507], 'C.': [508, 560, 577, 602, 604, 608, 630, 652, 664, 914, 927, 1073, 1226, 1523, 1545, 1560, 1595, 1603, 1688, 1705, 1724, 1754, 1805], 'Joachim,': [509, 561, 609, 928], 'J.': [510, 551, 562, 591, 720, 734, 747, 768, 789, 810, 827, 843, 944, 957, 998, 1017, 1032, 1043, 1046, 1213, 1216, 1218, 1236, 1247, 1531, 1542, 1543, 1553, 1557, 1558, 1577, 1605, 1661, 1693, 1743, 1752, 1757, 1782, 1784, 1795, 1806, 1817], 'K.': [511, 563, 646, 745, 1011, 1041, 1074, 1521, 1571, 1575, 1755, 1803, 1808], 'Gimzewski,': [512, 564], 'Chem.': [513, 593, 613, 634, 656, 668, 682, 690, 710, 722, 735, 737, 749, 769, 771, 787, 808, 829, 841, 862, 891, 906, 959, 999, 1001, 1019, 1034, 1048, 1201, 1220, 1238, 1251, 1533, 1549, 1579, 1599, 1650, 1664, 1694, 1796, 1819], 'Phys.': [514, 565, 929, 1237], 'Lett.': [515, 567, 919, 975, 1103, 1563], '1997,': [516, 614, 932, 1091, 1787], '265,': [517], '353.': [518], '[1c]': [522], 'Gourdon,': [524, 559, 611, 702, 1195], 'H.': [525, 556, 628, 764, 783, 798, 819, 1044, 1527, 1793], 'Tang,': [526, 557], '219.': [545], '[1d]': [549], 'V.': [550, 699, 955, 972, 985, 1228, 1647], 'Langlais,': [552], 'R.': [553, 554, 705, 728, 803, 1246, 1645, 1758, 1763], 'Schlittler,': [555], 'Rev.': [566, 691, 930], '1999,': [568, 830, 1021], '83,': [569], '2809.': [570], '[2]': [573], '[2a]': [576], 'Patoux,': [578, 603], 'J.-P.': [579, 585, 589, 606, 623, 644, 703, 853, 857, 859, 878, 885, 904, 916, 1198], 'Beley,': [582, 850, 877], 'S.': [583, 587, 650, 678, 687, 760, 763, 779, 782, 797, 800, 818, 821, 851, 902, 1029, 1084, 1540, 1555, 1703, 1809], 'Chodorowski-Kimmes,': [584, 852], 'Collin,': [586, 854, 879], 'James,': [588], 'Sauvage,': [590, 860, 886], 'Am.': [592, 748, 958, 1018, 1047, 1219, 1818], 'Soc.': [594, 750, 960, 1020, 1049, 1221, 1797, 1820], '120,': [596], '3717.': [597], '[2b]': [601], 'Inorg.': [612, 633, 655, 667, 681, 709, 1200, 1250], '36,': [615], '5037.': [616], '[2c]': [620], 'A.-C.': [621, 642], 'Ribou,': [622, 643], 'L.': [626, 761, 780, 801, 822, 883, 1030, 1781], 'Sachtleben,': [627], 'Li,': [629], 'W.': [631, 653, 1418, 1761, 1811, 1814], 'Spangler,': [632, 654], '1996,': [635, 711, 844, 1202, 1654], '35,': [636, 712, 1203, 1655], '3735.': [637], '[2d]': [641], 'Takahashi,': [647], 'T.': [648, 970, 996, 1009, 1215, 1517, 1643], 'Nihira,': [649], 'Tarutani,': [651], '1994,': [657, 866, 895, 1003, 1035, 1239, 1252, 1668, 1746], '33,': [658, 867, 896, 977, 1669], '1325.': [659], '[2e]': [663], 'Creutz,': [665], 'Progr.': [666, 680], '1983,': [669], '30,': [670, 1788], '[3]N.': [677], 'Hush,': [679, 688], '1967,': [683], '8,': [684], '391;': [685], 'N.': [686, 880, 1013, 1100], 'Coord.': [689], '1985,': [692], '64,': [693], '135.': [694], '[4]P.': [697], 'Lainé,': [698, 856], 'Marvaud,': [700], 'Argazzi,': [706], 'C.-A.': [707], 'Bignozzi,': [708], '711.': [713], '[5]M.': [716], 'Irie,': [717, 733, 742, 995, 1016, 1570], 'Mohri,': [719], 'Org.': [721, 828, 1033, 1532, 1578], '1988,': [723], '53,': [724], '803.': [725], 'Hanazawa,': [727], 'Sumiya,': [729], 'Y.': [730, 1098], 'Horikawa,': [731], 'Soc.,': [736, 770, 1000], 'Commun.': [738, 772, 907, 1002, 1090, 1550], '1992,': [739, 751, 976, 1821], '206;': [740], 'O.': [743, 1086], 'Miyatake,': [744], 'Uchida,': [746, 1012, 1576], '114,': [752, 1822], '8715.': [753], '[6]': [756], '[6a]': [759], 'Gilat,': [762, 781, 802, 823], 'Kawai,': [765, 784, 799, 820], 'J.-M.': [766, 785, 806, 824, 839, 1232], 'Lehn,': [767, 786, 807, 825, 840, 1233], '1993,': [773, 988], '1439.': [774], '[6b]': [778], 'Eur.': [788, 809, 826, 842, 1530], '1995,': [790, 811, 1580], '275.': [792], '[6c]': [796], 'Ponsinet,': [804], 'R.;': [805], '285.': [813], '[6d]': [817], '2359.': [831], '[6e]': [835], 'G.': [836, 887, 1717, 1719, 1726], 'Tsivgoulis,': [838], '2,': [845], '1399.': [846], '[7]M.': [849], 'P.': [855, 943, 1027, 1528, 1760], 'Angew.': [861, 890, 1649, 1663], 'Int.': [863, 892, 1651, 1665], 'Ed.': [864, 893, 1652, 1666], 'Engl.': [865, 894, 1653, 1667], '1775.': [868], '[8]J.-P.': [871], 'Sutter,': [872], 'D.': [873, 1519, 1690], 'Grove,': [875], 'Veldman,': [881], 'Spek,': [884], 'Van': [888], 'Koten,': [889], '1282.': [897], '[9]C.': [900], '663.': [909], '[10]S.': [912], 'Tetrahedron': [918, 974, 1102, 1562], '39,': [921, 1565], '7873.': [922], '[11]M.': [925], 'Magoga,': [926], 'B': [931], '56,': [933], '4722.': [934], '[12]Metal-Catalysed': [937], 'Cross-coupling': [938], 'Reactions': [939], 'F.': [941, 1547], 'Diederich,': [942], 'Stang),': [945], 'Wiley-VCH,': [946], 'Weinheim,': [947], 'chapter': [949], '5.': [950], '[13]P.': [953], 'Stang,': [954, 967, 982], 'Zhdankin,': [956, 973, 986], '1991,': [961], '113,': [962], '4571.': [963], '[14]P.': [966], 'Schwarz,': [969, 984], 'Blume,': [971], '6759.': [978], '[15]P.': [981], '35.': [989], '[16]T.': [992], 'Saika,': [993], 'Shimidzu,': [997], '2123.': [1004], '[17]S.': [1007], 'Kobatake,': [1008], 'Yamada,': [1010], 'Kato,': [1014], '121,': [1022], '2380.': [1023], '[18]B.': [1026], 'Warner,': [1028], 'Buchwald,': [1031], '59,': [1036], '5822.': [1037], '[19]J.': [1040], 'Stille,': [1042], 'Simpson,': [1045], '1987,': [1050, 1609], '109,': [1051], '2138.': [1052], '[20]A': [1055], 'related': [1056, 1586], 'example': [1057, 1587], 'Glaser-like': [1060], 'reaction': [1061], 'involving': [1062, 1172], 'organic': [1064], 'halide': [1065], 'as': [1066, 1125, 1130], 'oxidizer': [1067], 'reported:': [1069], 'E.': [1071, 1196], 'Wright,': [1072], 'Lowe-Ma,': [1075], 'Organometallics': [1076], '1990,': [1077, 1428, 1696], '9,': [1078], '347.': [1079], '[21]R.': [1082], 'Durr,': [1083], 'Cossu,': [1085], 'De': [1087], 'Lucchi,': [1088], 'Synth.': [1089], '27,': [1092, 1747], '1369.': [1093], '[22]K.': [1096], 'Sonogashira,': [1097], 'Tohda,': [1099], 'Hagihara,': [1101], '1975,': [1104], '50,': [1105], '4467.': [1106], '[23]Due': [1109], 'chirality': [1112, 1156, 1180], 'organometallic': [1115], 'group': [1116], '(Λ': [1117], 'Δ': [1119], 'configuration),': [1120], 'are': [1123, 1141, 1262, 1375], 'obtained': [1124, 1495], 'mixtures': [1126], 'stereoisomers': [1128], 'such': [1129], 'ΛΛ,': [1131], 'ΔΛ': [1132, 1134], 'However,': [1137], 'chiral': [1139], 'centers': [1140, 1161, 1184], 'generally': [1142], 'sufficiently': [1143], 'far': [1144], 'apart': [1145], 'their': [1147], 'steric': [1148], 'interaction': [1149], 'negligible,': [1152], 'so': [1153], 'that': [1154], 'two': [1159], 'metal': [1160, 1183], 'considered': [1164, 1264], 'independent.': [1167], 'Moreover,': [1168], 'similar': [1170], 'examples': [1171], 'Ru(bipy)2-like': [1173], 'terminal': [1174], 'units,': [1175, 1505], 'no': [1176], 'consequences': [1177], 'reported,': [1186], 'neither': [1187], 'on': [1188, 1206], 'NMR': [1190, 1274], 'spectra': [1191], '(J.': [1192], 'Bolger,': [1193], 'Ishow,': [1197], '2937),': [1204], 'nor': [1205], 'electrochemical': [1208], 'spectroscopic': [1210], 'behavior': [1211], '(M.': [1212], 'Powers,': [1214], 'Meyer,': [1217], '1980,': [1222], '102,': [1223], '1289;': [1224], 'Benniston,': [1227], 'Goulle,': [1229], 'Harriman,': [1231], 'B.': [1234], 'Marczinke,': [1235], '98,': [1240], '7798).': [1241], 'See': [1242], 'also': [1243], 'review:': [1245], 'Crutchley,': [1248], 'Adv.': [1249], '41,': [1253, 1610], '273,': [1254], 'Thus,': [1258], 'stereochemical': [1260], 'rest': [1267], 'paper.': [1270], '[24]1H': [1273], '(250': [1275], 'MHz,': [1276], 'CD3OD,': [1277], '20': [1278], '°C)': [1279], '12a:': [1281], 'δ': [1282], '2.02': [1284], '(s,': [1285, 1289], '3': [1286, 1294], 'H),': [1287, 1291, 1295], '7.34': [1288], '7.40−7.46': [1292], '(m,': [1293, 1297], '7.58−7.60': [1296], '2': [1298], 'H).': [1299], 'Electrochemistry:': [1300], 'irreversible': [1301], 'at': [1303], '1.04': [1304], 'V': [1305], 'vs': [1306], 'SCE': [1307], 'MeCN.': [1309], 'Colorless': [1310], '“open”': [1311], 'compound': [1312], '12a': [1313], 'undergoes': [1314], 'photocyclization': [1315], 'irradiation': [1317], 'UV': [1319], 'light,': [1320, 1472], '“closed”': [1324], 'cobalt-blue': [1325], 'isomer': [1326], '12b.': [1327], '1.6·10−5': [1330], 'M': [1331], 'solution': [1332, 1736], 'MeCN,': [1334], 'photostationary': [1336], 'state': [1337], 'reached': [1339], 'within': [1340], '25': [1341], 's': [1342, 1345], '(cf.': [1343], '30': [1344], '8).': [1347], 'UV/Vis': [1348], 'MeCN:': [1350], 'λmax': [1351], '(nm)': [1352], '(ϵ': [1353], '[M−1': [1354], 'cm−1]):': [1355], '(12a):': [1358], '306': [1359], '(61250);': [1360], '(12b):': [1363], '604': [1364], '(21900).': [1365], '[25]In': [1368], 'expression,': [1370], 'Vab,': [1371], 'ν¯,': [1372], 'Δν¯1/2': [1374], 'cm−1,': [1377, 1382], 'ϵmax': [1378], 'mol−1': [1380], 'L': [1381], 'RMM': [1384], 'Å.': [1387], 'The': [1388, 1447], 'proportionality': [1389], 'factor': [1390, 1452], '0.0205': [1391], 'comes': [1392], 'from': [1393], 'definition': [1396], 'oscillator': [1399], 'strength': [1400], 'f': [1401, 1411], 'terms': [1403], 'experimental': [1405], 'quantities,': [1406], 'relation': [1409], 'moment': [1415], 'μtr': [1416, 1436], '(P.': [1417], 'Atkins,': [1419], 'Physical': [1420], 'Chemistry,': [1421], '4th': [1422], 'ed.,': [1423], 'Oxford': [1424, 1775], 'University': [1425, 1772], 'Press,': [1426], 'Oxford,': [1427, 1774], 'pp.': [1429], '503−504),': [1430], '(iii)': [1432], 'expression': [1434, 1449], 'particular': [1439], 'case': [1440, 1634], 'transitions,': [1443], 'according': [1444], 'Hush.[3]': [1446], 'literal': [1448], '[3': [1454], 'hCϵ0(ln': [1455], '10)/4': [1456], 'π2': [1457], 'NA': [1458, 1480], 'e2]1/2': [1459], '(π/ln': [1460], '2)1/4': [1461], 'where': [1462], 'h': [1463], 'Planck’s': [1465], 'constant,': [1466], 'C': [1467], 'velocity': [1470], 'ϵ0': [1473], 'permittivity': [1476], 'vacuum,': [1479], 'Avogadro’s': [1482], 'number,': [1483], 'e': [1485], 'elementary': [1488], 'charge;': [1489], 'value': [1491], '6.513·10−12': [1493, 1509], 'SI': [1497], 'units.': [1498], 'Converted': [1499], 'common': [1503], 'non-SI': [1504], 'result': [1507], '×': [1510], '(1000)1/2·108,': [1511], 'i.e.,': [1512], '0.0205.': [1513], '[26]A.': [1516], 'Bens,': [1518], 'Frewert,': [1520], 'Kodatis,': [1522], 'Kryschi,': [1524], 'H.-D.': [1525], 'Martin,': [1526], 'Trommsdorff,': [1529], '2333.': [1535], '[27]J.': [1538], 'Lacour,': [1539, 1554], 'Torche-Haldimann,': [1541], 'Jodry,': [1544, 1559], 'Ginglinger,': [1546, 1561], 'Favarger,': [1548], '1733;': [1552], 'Barchéchath,': [1556], '567.': [1566], '[28]M.': [1569], 'Sakemura,': [1572], 'Okinaka,': [1574], '60,': [1581], '8305.': [1582], '[29]A': [1585], 'ring': [1589, 1636], 'opening': [1590], 'described:': [1594], 'Pac,': [1596, 1604], 'Pure': [1597], 'Appl.': [1598, 1744, 1785], '1986,': [1600], '58,': [1601], '1249.': [1602], 'Photochem.': [1606], 'Photobiol.': [1607], 'A': [1608], '37.': [1611], 'It': [1612], 'involves': [1613], 'photoinduced': [1615, 1639], 'strained': [1619], 'carbocycle': [1620], '(cyclobutane)': [1621], 'sensitizer,': [1624], 'resulting': [1625], 'bond': [1627], 'cleavage': [1628], 'former.': [1631], 'another': [1633], 'reopening': [1637], 'transfer,': [1641], 'see:': [1642], 'Carell,': [1644], 'Epple,': [1646], 'Gramlich,': [1648], '620.': [1656], '[30]R.': [1659], 'Weiss,': [1660], 'Seubert,': [1662], '891.': [1670], '[31]Cerius2,': [1673], 'Biosym/Molecular': [1674], 'Simulations,': [1675], 'San': [1676], 'Diego,': [1677], 'CA,': [1678], 'USA.': [1679], '[32]CACAO': [1682], 'PC': [1683], 'Version': [1684], '4.0,': [1685], '1994.': [1687], 'Mealli,': [1689], 'Proserpio,': [1692], 'Educ.': [1695], '67,': [1697], '399.': [1698], '[33]J.-P.': [1701], 'Mol.': [1707], 'Cryst.': [1708], 'Liq.': [1709], 'Cryst.,': [1710], 'press.': [1712], '[34]A.': [1715], 'Altomare,': [1716], 'Cascarano,': [1718], 'Giacovazzo,': [1720], 'Guagliardi,': [1722], 'Burla,': [1725], 'Polidori,': [1727], 'Camalli,': [1729], '“SIR92': [1730], 'program': [1733], 'automatic': [1735], 'crystal': [1738], 'structures': [1739], 'direct': [1741], 'methods”,': [1742], 'Crystallogr.': [1745, 1786], '435.': [1748], '[35]D.': [1751], 'Watkin,': [1753], 'Prout,': [1756], 'Carruthers,': [1759], 'Betteridge,': [1762], 'I.': [1764], 'Cooper,': [1765], 'CRYSTALS': [1766], '11,': [1768], 'Chemical': [1769], 'Crystallography': [1770], 'Laboratory,': [1771], '(UK).': [1776], '[36]ORTEP': [1779], 'III:': [1780], 'Farrugia,': [1783], '565.': [1789], '[37]K.': [1792], 'Pausacker,': [1794], '1953,': [1798], '107.': [1799], '[38]A.': [1802], 'Rappé,': [1804], 'Casewit,': [1807], 'Colwell,': [1810], 'Goddard,': [1813], 'Skiff,': [1816], '10024.': [1823], 'Citing': [1826], 'Literature': [1827], 'Volume2000,': [1828], 'Issue7July': [1829], '2000Pages': [1830], 'ReferencesRelatedInformation': [1832]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W1994773831', 'counts_by_year': [{'year': 2023, 'cited_by_count': 1}, {'year': 2022, 'cited_by_count': 1}, {'year': 2021, 'cited_by_count': 3}, {'year': 2020, 'cited_by_count': 5}, {'year': 2019, 'cited_by_count': 5}, {'year': 2018, 'cited_by_count': 4}, {'year': 2017, 'cited_by_count': 5}, {'year': 2016, 'cited_by_count': 9}, {'year': 2015, 'cited_by_count': 5}, {'year': 2014, 'cited_by_count': 11}, {'year': 2013, 'cited_by_count': 17}, {'year': 2012, 'cited_by_count': 13}], 'updated_date': '2024-12-14T15:47:35.916061', 'created_date': '2016-06-24'}