Title: Phosphorescence spectra and triplet state lifetimes of palladium octaethylporphyrin, palladium octaethylchlorin and palladium 2,3-dimethyloctaethylisobacteriochlorin at 77 K
Abstract: The phosphorescence spectra and triplet state lifetimes of palladium octaethylporphyrin (PdOEP), palladium octaethylchlorin (PdOEC) and palladium 2,3-dimethyloctaethylisobacteriochlorin (PdOEiBC) in n-octane Shpolskii matrices at 77 K are reported. The lifetime and T1/S0 origin energy of each complex are: PdOEP, 1.90±0.04 ms, 15162 cm−1; PdOEC, 0.43±0.03 ms, 12547 cm−1 and PdOEiBC, 0.59±0.03 ms, 12863 cm−1.
Publication Year: 2003
Publication Date: 2003-03-01
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']
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Cited By Count: 9
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