Get quick answers to your questions about the article from our AI researcher chatbot
{'id': 'https://openalex.org/W1991958952', 'doi': 'https://doi.org/10.1021/ic034301w', 'title': 'Bond Dissociation Energy and Lewis Acidity of the Xenon Fluoride Cation', 'display_name': 'Bond Dissociation Energy and Lewis Acidity of the Xenon Fluoride Cation', 'publication_year': 2003, 'publication_date': '2003-06-19', 'ids': {'openalex': 'https://openalex.org/W1991958952', 'doi': 'https://doi.org/10.1021/ic034301w', 'mag': '1991958952', 'pmid': 'https://pubmed.ncbi.nlm.nih.gov/12844301'}, 'language': 'en', 'primary_location': {'is_oa': False, 'landing_page_url': 'https://doi.org/10.1021/ic034301w', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S171072222', 'display_name': 'Inorganic Chemistry', 'issn_l': '0020-1669', 'issn': ['0020-1669', '1520-510X'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320006', 'host_organization_name': 'American Chemical Society', 'host_organization_lineage': ['https://openalex.org/P4310320006'], 'host_organization_lineage_names': ['American Chemical Society'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}, 'type': 'article', 'type_crossref': 'journal-article', 'indexed_in': ['crossref', 'pubmed'], 'open_access': {'is_oa': False, 'oa_status': 'closed', 'oa_url': None, 'any_repository_has_fulltext': False}, 'authorships': [{'author_position': 'first', 'author': {'id': 'https://openalex.org/A5032706583', 'display_name': 'Ian H. Krouse', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I219193219', 'display_name': 'Purdue University West Lafayette', 'ror': 'https://ror.org/02dqehb95', 'country_code': 'US', 'type': 'education', 'lineage': ['https://openalex.org/I219193219']}], 'countries': ['US'], 'is_corresponding': False, 'raw_author_name': 'Ian H. Krouse', 'raw_affiliation_strings': ['Department of Chemistry, Purdue University, West Lafayette, Indiana 47907-2084'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry, Purdue University, West Lafayette, Indiana 47907-2084', 'institution_ids': ['https://openalex.org/I219193219']}]}, {'author_position': 'last', 'author': {'id': 'https://openalex.org/A5054489541', 'display_name': 'Paul G. Wenthold', 'orcid': 'https://orcid.org/0000-0002-8257-3907'}, 'institutions': [{'id': 'https://openalex.org/I219193219', 'display_name': 'Purdue University West Lafayette', 'ror': 'https://ror.org/02dqehb95', 'country_code': 'US', 'type': 'education', 'lineage': ['https://openalex.org/I219193219']}], 'countries': ['US'], 'is_corresponding': False, 'raw_author_name': 'Paul G. Wenthold', 'raw_affiliation_strings': ['Department of Chemistry, Purdue University, West Lafayette, Indiana 47907-2084'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry, Purdue University, West Lafayette, Indiana 47907-2084', 'institution_ids': ['https://openalex.org/I219193219']}]}], 'institution_assertions': [], 'countries_distinct_count': 1, 'institutions_distinct_count': 1, 'corresponding_author_ids': [], 'corresponding_institution_ids': [], 'apc_list': None, 'apc_paid': None, 'fwci': 1.19, 'has_fulltext': True, 'fulltext_origin': 'ngrams', 'cited_by_count': 20, 'citation_normalized_percentile': {'value': 0.636538, 'is_in_top_1_percent': False, 'is_in_top_10_percent': False}, 'cited_by_percentile_year': {'min': 85, 'max': 86}, 'biblio': {'volume': '42', 'issue': '14', 'first_page': '4293', 'last_page': '4298'}, 'is_retracted': False, 'is_paratext': False, 'primary_topic': {'id': 'https://openalex.org/T12646', 'display_name': 'Inorganic Fluorides and Related Compounds', 'score': 0.9997, 'subfield': {'id': 'https://openalex.org/subfields/1604', 'display_name': 'Inorganic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, 'topics': [{'id': 'https://openalex.org/T12646', 'display_name': 'Inorganic Fluorides and Related Compounds', 'score': 0.9997, 'subfield': {'id': 'https://openalex.org/subfields/1604', 'display_name': 'Inorganic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T10002', 'display_name': 'Advanced Chemical Physics Studies', 'score': 0.9993, 'subfield': {'id': 'https://openalex.org/subfields/3107', 'display_name': 'Atomic and Molecular Physics, and Optics'}, 'field': {'id': 'https://openalex.org/fields/31', 'display_name': 'Physics and Astronomy'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T10683', 'display_name': 'Mass Spectrometry Techniques and Applications', 'score': 0.9935, 'subfield': {'id': 'https://openalex.org/subfields/1607', 'display_name': 'Spectroscopy'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}], 'keywords': [{'id': 'https://openalex.org/keywords/bond-dissociation-energy', 'display_name': 'Bond-dissociation energy', 'score': 0.84671307}, {'id': 'https://openalex.org/keywords/bond-energy', 'display_name': 'Bond energy', 'score': 0.68451184}, {'id': 'https://openalex.org/keywords/krypton', 'display_name': 'Krypton', 'score': 0.46456257}, {'id': 'https://openalex.org/keywords/collision-induced-dissociation', 'display_name': 'Collision-induced dissociation', 'score': 0.45340863}], 'concepts': [{'id': 'https://openalex.org/C185592680', 'wikidata': 'https://www.wikidata.org/wiki/Q2329', 'display_name': 'Chemistry', 'level': 0, 'score': 0.93489003}, {'id': 'https://openalex.org/C548442186', 'wikidata': 'https://www.wikidata.org/wiki/Q1106', 'display_name': 'Xenon', 'level': 2, 'score': 0.8737238}, {'id': 'https://openalex.org/C62396407', 'wikidata': 'https://www.wikidata.org/wiki/Q863696', 'display_name': 'Bond-dissociation energy', 'level': 3, 'score': 0.84671307}, {'id': 'https://openalex.org/C102931765', 'wikidata': 'https://www.wikidata.org/wiki/Q189673', 'display_name': 'Dissociation (chemistry)', 'level': 2, 'score': 0.71824753}, {'id': 'https://openalex.org/C122032599', 'wikidata': 'https://www.wikidata.org/wiki/Q2914535', 'display_name': 'Bond energy', 'level': 3, 'score': 0.68451184}, {'id': 'https://openalex.org/C522602180', 'wikidata': 'https://www.wikidata.org/wiki/Q654', 'display_name': 'Neon', 'level': 3, 'score': 0.63481575}, {'id': 'https://openalex.org/C198291218', 'wikidata': 'https://www.wikidata.org/wiki/Q190382', 'display_name': 'Ionization', 'level': 3, 'score': 0.5011625}, {'id': 'https://openalex.org/C162356407', 'wikidata': 'https://www.wikidata.org/wiki/Q180809', 'display_name': 'Mass spectrometry', 'level': 2, 'score': 0.49982715}, {'id': 'https://openalex.org/C147192597', 'wikidata': 'https://www.wikidata.org/wiki/Q483769', 'display_name': 'Ionization energy', 'level': 4, 'score': 0.47833252}, {'id': 'https://openalex.org/C521692839', 'wikidata': 'https://www.wikidata.org/wiki/Q888', 'display_name': 'Krypton', 'level': 3, 'score': 0.46456257}, {'id': 'https://openalex.org/C547737533', 'wikidata': 'https://www.wikidata.org/wiki/Q696', 'display_name': 'Argon', 'level': 2, 'score': 0.45794386}, {'id': 'https://openalex.org/C176107965', 'wikidata': 'https://www.wikidata.org/wiki/Q3710336', 'display_name': 'Collision-induced dissociation', 'level': 4, 'score': 0.45340863}, {'id': 'https://openalex.org/C184779094', 'wikidata': 'https://www.wikidata.org/wiki/Q26383', 'display_name': 'Atomic physics', 'level': 1, 'score': 0.42907727}, {'id': 'https://openalex.org/C75473681', 'wikidata': 'https://www.wikidata.org/wiki/Q188651', 'display_name': 'Photochemistry', 'level': 1, 'score': 0.36448568}, {'id': 'https://openalex.org/C113196181', 'wikidata': 'https://www.wikidata.org/wiki/Q485223', 'display_name': 'Analytical Chemistry (journal)', 'level': 2, 'score': 0.3574578}, {'id': 'https://openalex.org/C147789679', 'wikidata': 'https://www.wikidata.org/wiki/Q11372', 'display_name': 'Physical chemistry', 'level': 1, 'score': 0.34678108}, {'id': 'https://openalex.org/C145148216', 'wikidata': 'https://www.wikidata.org/wiki/Q36496', 'display_name': 'Ion', 'level': 2, 'score': 0.31453562}, {'id': 'https://openalex.org/C32909587', 'wikidata': 'https://www.wikidata.org/wiki/Q11369', 'display_name': 'Molecule', 'level': 2, 'score': 0.21452647}, {'id': 'https://openalex.org/C31827203', 'wikidata': 'https://www.wikidata.org/wiki/Q874296', 'display_name': 'Tandem mass spectrometry', 'level': 3, 'score': 0.13530591}, {'id': 'https://openalex.org/C178790620', 'wikidata': 'https://www.wikidata.org/wiki/Q11351', 'display_name': 'Organic chemistry', 'level': 1, 'score': 0.10006702}, {'id': 'https://openalex.org/C121332964', 'wikidata': 'https://www.wikidata.org/wiki/Q413', 'display_name': 'Physics', 'level': 0, 'score': 0.0}, {'id': 'https://openalex.org/C43617362', 'wikidata': 'https://www.wikidata.org/wiki/Q170050', 'display_name': 'Chromatography', 'level': 1, 'score': 0.0}], 'mesh': [], 'locations_count': 2, 'locations': [{'is_oa': False, 'landing_page_url': 'https://doi.org/10.1021/ic034301w', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S171072222', 'display_name': 'Inorganic Chemistry', 'issn_l': '0020-1669', 'issn': ['0020-1669', '1520-510X'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320006', 'host_organization_name': 'American Chemical Society', 'host_organization_lineage': ['https://openalex.org/P4310320006'], 'host_organization_lineage_names': ['American Chemical Society'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}, {'is_oa': False, 'landing_page_url': 'https://pubmed.ncbi.nlm.nih.gov/12844301', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S4306525036', 'display_name': 'PubMed', 'issn_l': None, 'issn': None, 'is_oa': False, 'is_in_doaj': False, 'is_core': False, 'host_organization': 'https://openalex.org/I1299303238', 'host_organization_name': 'National Institutes of Health', 'host_organization_lineage': ['https://openalex.org/I1299303238'], 'host_organization_lineage_names': ['National Institutes of Health'], 'type': 'repository'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}], 'best_oa_location': None, 'sustainable_development_goals': [], 'grants': [], 'datasets': [], 'versions': [], 'referenced_works_count': 46, 'referenced_works': ['https://openalex.org/W1970269144', 'https://openalex.org/W1973303022', 'https://openalex.org/W1974623739', 'https://openalex.org/W1974667766', 'https://openalex.org/W1976212362', 'https://openalex.org/W1982249962', 'https://openalex.org/W1982885455', 'https://openalex.org/W1984614201', 'https://openalex.org/W1993475546', 'https://openalex.org/W1994927385', 'https://openalex.org/W1997186396', 'https://openalex.org/W1997352946', 'https://openalex.org/W2003248685', 'https://openalex.org/W2007132443', 'https://openalex.org/W2009616470', 'https://openalex.org/W2010042115', 'https://openalex.org/W2023550014', 'https://openalex.org/W2031856796', 'https://openalex.org/W2036818473', 'https://openalex.org/W2045654812', 'https://openalex.org/W2045679870', 'https://openalex.org/W2048968467', 'https://openalex.org/W2058541740', 'https://openalex.org/W2059417079', 'https://openalex.org/W2072443558', 'https://openalex.org/W2078843151', 'https://openalex.org/W2079734496', 'https://openalex.org/W2084213816', 'https://openalex.org/W2086957099', 'https://openalex.org/W2087672213', 'https://openalex.org/W2088561237', 'https://openalex.org/W2093712968', 'https://openalex.org/W2093755038', 'https://openalex.org/W2102548430', 'https://openalex.org/W2153765202', 'https://openalex.org/W2327469115', 'https://openalex.org/W2950016663', 'https://openalex.org/W2951322569', 'https://openalex.org/W2951588037', 'https://openalex.org/W2952871119', 'https://openalex.org/W3136408545', 'https://openalex.org/W3217528490', 'https://openalex.org/W4243094954', 'https://openalex.org/W4254256090', 'https://openalex.org/W4256022816', 'https://openalex.org/W4301806259'], 'related_works': ['https://openalex.org/W4302763282', 'https://openalex.org/W270253631', 'https://openalex.org/W2384631984', 'https://openalex.org/W2076833660', 'https://openalex.org/W2045309723', 'https://openalex.org/W2034480035', 'https://openalex.org/W2002804196', 'https://openalex.org/W1991958952', 'https://openalex.org/W1973172439', 'https://openalex.org/W1798314630'], 'abstract_inverted_index': {'This': [0], 'study': [1], 'focuses': [2], 'upon': [3], 'the': [4, 14, 18, 21, 107, 115, 125, 164, 168, 173, 176, 185], 'Lewis': [5], 'acid': [6], 'reactivity': [7], 'of': [8, 20, 25, 31, 59, 87, 114, 147, 172, 188], 'XeF+': [9, 32, 116, 143], 'with': [10, 41, 49, 66, 97, 149], 'various': [11], 'bases': [12], 'in': [13, 133], 'gas': [15], 'phase': [16], 'and': [17, 44, 64, 100, 144, 159], 'determination': [19], 'bond': [22, 28, 56], 'dissociation': [23, 29, 40, 57, 120], 'energy': [24, 30], 'XeF+.': [26], 'The': [27], 'has': [33], 'been': [34, 131, 154, 182], 'measured': [35], 'by': [36, 139, 145, 157], 'using': [37, 79], 'energy-resolved': [38], 'collision-induced': [39], 'neon,': [42], 'argon,': [43], 'xenon': [45, 81, 189], 'target': [46, 51, 68, 109], 'gases.': [47], 'Experiments': [48], 'neon': [50], 'yield': [52], 'a': [53, 70, 80, 83, 134], '298': [54], 'K': [55], 'enthalpy': [58], '2.81': [60], '±': [61, 75, 89], '0.09': [62], 'eV,': [63], 'those': [65], 'argon': [67], 'give': [69, 111], 'similar': [71], 'value': [72, 86], 'at': [73, 121], '2.83': [74], '0.12': [76], 'eV.': [77], 'When': [78], 'target,': [82], 'significantly': [84], 'lower': [85], '1.95': [88], '0.16': [90], 'eV': [91], 'was': [92], 'observed,': [93], 'which': [94], 'corresponds': [95], 'closely': [96], 'previous': [98], 'measurements': [99], 'theoretical': [101], 'predictions.': [102], 'It': [103], 'is': [104, 161], 'proposed': [105], 'that': [106, 163, 180], 'lighter': [108], 'gases': [110], 'inefficient': [112], 'excitation': [113], 'vibration': [117], 'leading': [118], 'to': [119, 142], 'energies': [122, 171], 'higher': [123], 'than': [124], 'BDE.': [126], 'Novel': [127], 'xenon-base': [128], 'adducts': [129], 'have': [130, 153, 181], 'prepared': [132, 183], 'flowing': [135], 'afterglow': [136], 'mass': [137], 'spectrometer': [138], 'termolecular': [140], 'addition': [141], 'reaction': [146], 'base': [148], 'XeF+(H2O).': [150], 'New': [151], 'species': [152, 179], 'characterized': [155], 'qualitatively': [156], 'CID,': [158], 'it': [160], 'found': [162], 'products': [165], 'formed': [166], 'reflect': [167], 'relative': [169], 'ionization': [170], 'fragments.': [174], 'Among': [175], 'new': [177], 'xenon-containing': [178], 'are': [184], 'first': [186], 'examples': [187], 'carbonyls.': [190]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W1991958952', 'counts_by_year': [{'year': 2020, 'cited_by_count': 2}, {'year': 2018, 'cited_by_count': 2}, {'year': 2017, 'cited_by_count': 1}, {'year': 2013, 'cited_by_count': 3}], 'updated_date': '2024-12-17T16:01:02.728571', 'created_date': '2016-06-24'}