Linkage isomerization and electrochemical behavior of two geometrical isomers of dichlorobis(dimethylsulfoxide)bis(<i>t</i>-butylpyridine)ruthenium(II)

Name: Work Video:
Duration: 3 min 30 s
Denise de Oliveira Silva; Henrique E. Toma
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'isomers': [27], '[RuCl': [29], '(S-dmso)': [31], '].': [35], 'cct': [37], 'isomer': [38, 61, 115], 'exhibits': [39], 'a': [40, 76, 89], 'reversible': [41], 'cyclic': [42], 'voltammogram,': [43], 'ascribed': [44], 'Ru': [47, 112], 'III/II': [48], 'redox': [49], 'couple': [50], 'E': [52, 66], '1/2': [53, 67], '1.12': [55], 'V': [56], 'versus': [57], 'SHE.': [58], 'ccc': [60, 114], 'can': [62], 'be': [63], 'oxidized': [64, 73], 'at': [65], '1.27': [69], 'V;': [70], 'however,': [71], 'species': [74], 'undergoes': [75], 'relaxation': [77], 'equilibrium,': [78], '(K': [79], 's→o': [80, 94], '1.59),': [82], 'involving': [83], 'S-to-O': [85], 'linkage': [86], 'isomerization': [87, 108], 'coordinated': [90], 'dmso': [91, 127], 'ligand': [92], '(k': [93], '1.9': [96], 's': [97, 104], '−1': [98, 105], 'k': [100], 'O→S': [101], '1.2': [103], ').': [106], 'III': [113], 'is': [116], 'discussed': [117], 'terms': [119], 'competitive': [122], 'effects': [123], 'between': [124], 'S-bound': [126], 'tbpy': [130], 'ligands.': [131]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W1988927730', 'counts_by_year': [{'year': 2020, 'cited_by_count': 1}, {'year': 2019, 'cited_by_count': 3}, {'year': 2018, 'cited_by_count': 1}, {'year': 2016, 'cited_by_count': 1}, {'year': 2015, 'cited_by_count': 2}, {'year': 2014, 'cited_by_count': 1}, {'year': 2013, 'cited_by_count': 1}, {'year': 2012, 'cited_by_count': 2}], 'updated_date': '2024-12-14T01:11:52.009878', 'created_date': '2016-06-24'}
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