Title: The thermochemistry of polyoxides and polyoxy radicals
Abstract:Abstract A new estimate is derived for the group additivity contribution ΔH [O—(O) 2 ] = 55 ± 6 kJ mol −1 , based upon recent experimental data, which enables heats of formation and bond dissociation ...Abstract A new estimate is derived for the group additivity contribution ΔH [O—(O) 2 ] = 55 ± 6 kJ mol −1 , based upon recent experimental data, which enables heats of formation and bond dissociation energies to be estimated for species RO n R and RO (R = H, CH 3 , and CF 3 ). Semi‐empirical MNDO calculated heats of formation, for these species, provide independent support for the new thermochemical estimates. The results are also consistent with other theoretical and experimental evidence.Read More
Publication Year: 1988
Publication Date: 1988-06-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 68
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