Title: Effect of carbenoid structure on the reactivity of rhodium-stabilized carbenoids
Abstract: The outcome of rhodium(II) pivalate catalyzed decomposition of diaozoacetates in the presence of cyclohexane is highly dependent on carbenoid structure. Carbenoids derived from phenyldiazoacetates or diazoketoesters undergo high yielding intermolecular CH insertions while other carbenoid systems undergo rearrangements, dimerization or trimerization.
Publication Year: 1998
Publication Date: 1998-06-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 52
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