Toward Amorphous Conductors: Enhanced Conductivity of Doped Polyaniline via Interchain Crosslinking Promoted by Acid‐Functionalized Aluminum Quinolines

Name: Work Video:
Duration: 3 min 30 s
Description: Polyaniline is doped with an Alq3 homologue endowed with sulfonic acid functionalities. The design of the dopant, which favors the formation of a crosslinked network between the polymer chains, along with its semiconducting electrical properties, highly enhance charge transport inside the amorphous phase of the material (see figure).
Massimiliano Massi; Cristiano Albonetti; M. Facchini; Massimiliano Cavallini; Fabio Biscarini
{'id': 'https://openalex.org/W1983599785', 'doi': 'https://doi.org/10.1002/adma.200600465', 'title': 'Toward Amorphous Conductors: Enhanced Conductivity of Doped Polyaniline via Interchain Crosslinking Promoted by Acid‐Functionalized Aluminum Quinolines', 'display_name': 'Toward Amorphous Conductors: Enhanced Conductivity of Doped Polyaniline via Interchain Crosslinking Promoted by Acid‐Functionalized Aluminum Quinolines', 'publication_year': 2006, 'publication_date': '2006-09-20', 'ids': {'openalex': 'https://openalex.org/W1983599785', 'doi': 'https://doi.org/10.1002/adma.200600465', 'mag': '1983599785'}, 'language': 'en', 'primary_location': {'is_oa': False, 'landing_page_url': 'https://doi.org/10.1002/adma.200600465', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S99352657', 'display_name': 'Advanced Materials', 'issn_l': '0935-9648', 'issn': ['0935-9648', '1521-4095'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': None, 'host_organization_name': None, 'host_organization_lineage': [], 'host_organization_lineage_names': [], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}, 'type': 'article', 'type_crossref': 'journal-article', 'indexed_in': ['crossref'], 'open_access': {'is_oa': False, 'oa_status': 'closed', 'oa_url': None, 'any_repository_has_fulltext': False}, 'authorships': [{'author_position': 'first', 'author': {'id': 'https://openalex.org/A5047782731', 'display_name': 'Massimiliano Massi', 'orcid': 'https://orcid.org/0000-0001-6949-4019'}, 'institutions': [{'id': 'https://openalex.org/I4210097224', 'display_name': 'Institute of Nanostructured Materials', 'ror': 'https://ror.org/00w6r1881', 'country_code': 'IT', 'type': 'facility', 'lineage': ['https://openalex.org/I4210097224', 'https://openalex.org/I4210155236']}], 'countries': ['IT'], 'is_corresponding': False, 'raw_author_name': 'M. Massi', 'raw_affiliation_strings': ['CNR‐Institute for the Study of Nanostructured Materials (ISMN), Nanotechnology of Multifunctional Materials Research Division, Via Gobetti 101, 40129 Bologna, Italy'], 'affiliations': [{'raw_affiliation_string': 'CNR‐Institute for the Study of Nanostructured Materials (ISMN), Nanotechnology of Multifunctional Materials Research Division, Via Gobetti 101, 40129 Bologna, Italy', 'institution_ids': ['https://openalex.org/I4210097224']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5062994557', 'display_name': 'Cristiano Albonetti', 'orcid': 'https://orcid.org/0000-0002-5665-0788'}, 'institutions': [{'id': 'https://openalex.org/I4210097224', 'display_name': 'Institute of Nanostructured Materials', 'ror': 'https://ror.org/00w6r1881', 'country_code': 'IT', 'type': 'facility', 'lineage': ['https://openalex.org/I4210097224', 'https://openalex.org/I4210155236']}], 'countries': ['IT'], 'is_corresponding': False, 'raw_author_name': 'C. Albonetti', 'raw_affiliation_strings': ['CNR‐Institute for the Study of Nanostructured Materials (ISMN), Nanotechnology of Multifunctional Materials Research Division, Via Gobetti 101, 40129 Bologna, Italy'], 'affiliations': [{'raw_affiliation_string': 'CNR‐Institute for the Study of Nanostructured Materials (ISMN), Nanotechnology of Multifunctional Materials Research Division, Via Gobetti 101, 40129 Bologna, Italy', 'institution_ids': ['https://openalex.org/I4210097224']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5102811991', 'display_name': 'M. Facchini', 'orcid': 'https://orcid.org/0000-0002-7511-0357'}, 'institutions': [{'id': 'https://openalex.org/I4210097224', 'display_name': 'Institute of Nanostructured Materials', 'ror': 'https://ror.org/00w6r1881', 'country_code': 'IT', 'type': 'facility', 'lineage': ['https://openalex.org/I4210097224', 'https://openalex.org/I4210155236']}], 'countries': ['IT'], 'is_corresponding': False, 'raw_author_name': 'M. Facchini', 'raw_affiliation_strings': ['CNR‐Institute for the Study of Nanostructured Materials (ISMN), Nanotechnology of Multifunctional Materials Research Division, Via Gobetti 101, 40129 Bologna, Italy'], 'affiliations': [{'raw_affiliation_string': 'CNR‐Institute for the Study of Nanostructured Materials (ISMN), Nanotechnology of Multifunctional Materials Research Division, Via Gobetti 101, 40129 Bologna, Italy', 'institution_ids': ['https://openalex.org/I4210097224']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5083307923', 'display_name': 'Massimiliano Cavallini', 'orcid': 'https://orcid.org/0000-0001-9802-0058'}, 'institutions': [{'id': 'https://openalex.org/I4210097224', 'display_name': 'Institute of Nanostructured Materials', 'ror': 'https://ror.org/00w6r1881', 'country_code': 'IT', 'type': 'facility', 'lineage': ['https://openalex.org/I4210097224', 'https://openalex.org/I4210155236']}], 'countries': ['IT'], 'is_corresponding': False, 'raw_author_name': 'M. Cavallini', 'raw_affiliation_strings': ['CNR‐Institute for the Study of Nanostructured Materials (ISMN), Nanotechnology of Multifunctional Materials Research Division, Via Gobetti 101, 40129 Bologna, Italy'], 'affiliations': [{'raw_affiliation_string': 'CNR‐Institute for the Study of Nanostructured Materials (ISMN), Nanotechnology of Multifunctional Materials Research Division, Via Gobetti 101, 40129 Bologna, Italy', 'institution_ids': ['https://openalex.org/I4210097224']}]}, {'author_position': 'last', 'author': {'id': 'https://openalex.org/A5018866764', 'display_name': 'Fabio Biscarini', 'orcid': 'https://orcid.org/0000-0001-6648-5803'}, 'institutions': [{'id': 'https://openalex.org/I4210097224', 'display_name': 'Institute of Nanostructured Materials', 'ror': 'https://ror.org/00w6r1881', 'country_code': 'IT', 'type': 'facility', 'lineage': ['https://openalex.org/I4210097224', 'https://openalex.org/I4210155236']}], 'countries': ['IT'], 'is_corresponding': False, 'raw_author_name': 'F. Biscarini', 'raw_affiliation_strings': ['CNR‐Institute for the Study of Nanostructured Materials (ISMN), Nanotechnology of Multifunctional Materials Research Division, Via Gobetti 101, 40129 Bologna, Italy'], 'affiliations': [{'raw_affiliation_string': 'CNR‐Institute for the Study of Nanostructured Materials (ISMN), Nanotechnology of Multifunctional Materials Research Division, Via Gobetti 101, 40129 Bologna, Italy', 'institution_ids': ['https://openalex.org/I4210097224']}]}], 'institution_assertions': [], 'countries_distinct_count': 1, 'institutions_distinct_count': 1, 'corresponding_author_ids': [], 'corresponding_institution_ids': [], 'apc_list': {'value': 5250, 'currency': 'USD', 'value_usd': 5250, 'provenance': 'doaj'}, 'apc_paid': None, 'fwci': 0.88, 'has_fulltext': True, 'fulltext_origin': 'ngrams', 'cited_by_count': 22, 'citation_normalized_percentile': {'value': 0.830946, 'is_in_top_1_percent': False, 'is_in_top_10_percent': False}, 'cited_by_percentile_year': {'min': 87, 'max': 88}, 'biblio': {'volume': '18', 'issue': '20', 'first_page': '2739', 'last_page': '2742'}, 'is_retracted': False, 'is_paratext': False, 'primary_topic': {'id': 'https://openalex.org/T10660', 'display_name': 'Conducting polymers and applications', 'score': 1.0, 'subfield': {'id': 'https://openalex.org/subfields/2507', 'display_name': 'Polymers and Plastics'}, 'field': {'id': 'https://openalex.org/fields/25', 'display_name': 'Materials Science'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, 'topics': [{'id': 'https://openalex.org/T10660', 'display_name': 'Conducting polymers and applications', 'score': 1.0, 'subfield': {'id': 'https://openalex.org/subfields/2507', 'display_name': 'Polymers and Plastics'}, 'field': {'id': 'https://openalex.org/fields/25', 'display_name': 'Materials Science'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T10045', 'display_name': 'Organic Electronics and Photovoltaics', 'score': 0.9997, 'subfield': {'id': 'https://openalex.org/subfields/2208', 'display_name': 'Electrical and Electronic Engineering'}, 'field': {'id': 'https://openalex.org/fields/22', 'display_name': 'Engineering'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T10338', 'display_name': 'Advanced Sensor and Energy Harvesting Materials', 'score': 0.9993, 'subfield': {'id': 'https://openalex.org/subfields/2204', 'display_name': 'Biomedical Engineering'}, 'field': {'id': 'https://openalex.org/fields/22', 'display_name': 'Engineering'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}], 'keywords': [{'id': 'https://openalex.org/keywords/sulfonic-acid', 'display_name': 'Sulfonic acid', 'score': 0.78379166}, {'id': 'https://openalex.org/keywords/polyaniline-nanofibers', 'display_name': 'Polyaniline nanofibers', 'score': 0.47981238}], 'concepts': [{'id': 'https://openalex.org/C192562407', 'wikidata': 'https://www.wikidata.org/wiki/Q228736', 'display_name': 'Materials science', 'level': 0, 'score': 0.9015206}, {'id': 'https://openalex.org/C191952053', 'wikidata': 'https://www.wikidata.org/wiki/Q15119237', 'display_name': 'Dopant', 'level': 3, 'score': 0.87473}, {'id': 'https://openalex.org/C2777580120', 'wikidata': 'https://www.wikidata.org/wiki/Q417637', 'display_name': 'Polyaniline', 'level': 4, 'score': 0.8267242}, {'id': 'https://openalex.org/C2778502040', 'wikidata': 'https://www.wikidata.org/wiki/Q250437', 'display_name': 'Sulfonic acid', 'level': 2, 'score': 0.78379166}, {'id': 'https://openalex.org/C56052488', 'wikidata': 'https://www.wikidata.org/wiki/Q103382', 'display_name': 'Amorphous solid', 'level': 2, 'score': 0.72440004}, {'id': 'https://openalex.org/C57863236', 'wikidata': 'https://www.wikidata.org/wiki/Q1130571', 'display_name': 'Doping', 'level': 2, 'score': 0.7117143}, {'id': 'https://openalex.org/C202374169', 'wikidata': 'https://www.wikidata.org/wiki/Q124291', 'display_name': 'Electrical conductor', 'level': 2, 'score': 0.6520703}, {'id': 'https://openalex.org/C133495861', 'wikidata': 'https://www.wikidata.org/wiki/Q412798', 'display_name': 'Conductive polymer', 'level': 3, 'score': 0.6435969}, {'id': 'https://openalex.org/C521977710', 'wikidata': 'https://www.wikidata.org/wiki/Q81163', 'display_name': 'Polymer', 'level': 2, 'score': 0.52649134}, {'id': 'https://openalex.org/C131540310', 'wikidata': 'https://www.wikidata.org/wiki/Q907564', 'display_name': 'Conductivity', 'level': 2, 'score': 0.5087877}, {'id': 'https://openalex.org/C42360764', 'wikidata': 'https://www.wikidata.org/wiki/Q83588', 'display_name': 'Chemical engineering', 'level': 1, 'score': 0.48234078}, {'id': 'https://openalex.org/C32785018', 'wikidata': 'https://www.wikidata.org/wiki/Q7226142', 'display_name': 'Polyaniline nanofibers', 'level': 5, 'score': 0.47981238}, {'id': 'https://openalex.org/C513153333', 'wikidata': 'https://www.wikidata.org/wiki/Q663', 'display_name': 'Aluminium', 'level': 2, 'score': 0.47794202}, {'id': 'https://openalex.org/C44280652', 'wikidata': 'https://www.wikidata.org/wiki/Q104837', 'display_name': 'Phase (matter)', 'level': 2, 'score': 0.4523273}, {'id': 'https://openalex.org/C171250308', 'wikidata': 'https://www.wikidata.org/wiki/Q11468', 'display_name': 'Nanotechnology', 'level': 1, 'score': 0.36232644}, {'id': 'https://openalex.org/C188027245', 'wikidata': 'https://www.wikidata.org/wiki/Q750446', 'display_name': 'Polymer chemistry', 'level': 1, 'score': 0.3550207}, {'id': 'https://openalex.org/C178790620', 'wikidata': 'https://www.wikidata.org/wiki/Q11351', 'display_name': 'Organic chemistry', 'level': 1, 'score': 0.1978457}, {'id': 'https://openalex.org/C159985019', 'wikidata': 'https://www.wikidata.org/wiki/Q181790', 'display_name': 'Composite material', 'level': 1, 'score': 0.18287238}, {'id': 'https://openalex.org/C49040817', 'wikidata': 'https://www.wikidata.org/wiki/Q193091', 'display_name': 'Optoelectronics', 'level': 1, 'score': 0.13340032}, {'id': 'https://openalex.org/C147789679', 'wikidata': 'https://www.wikidata.org/wiki/Q11372', 'display_name': 'Physical chemistry', 'level': 1, 'score': 0.07208425}, {'id': 'https://openalex.org/C185592680', 'wikidata': 'https://www.wikidata.org/wiki/Q2329', 'display_name': 'Chemistry', 'level': 0, 'score': 0.0}, {'id': 'https://openalex.org/C127413603', 'wikidata': 'https://www.wikidata.org/wiki/Q11023', 'display_name': 'Engineering', 'level': 0, 'score': 0.0}, {'id': 'https://openalex.org/C44228677', 'wikidata': 'https://www.wikidata.org/wiki/Q181898', 'display_name': 'Polymerization', 'level': 3, 'score': 0.0}], 'mesh': [], 'locations_count': 1, 'locations': [{'is_oa': False, 'landing_page_url': 'https://doi.org/10.1002/adma.200600465', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S99352657', 'display_name': 'Advanced Materials', 'issn_l': '0935-9648', 'issn': ['0935-9648', '1521-4095'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': None, 'host_organization_name': None, 'host_organization_lineage': [], 'host_organization_lineage_names': [], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}], 'best_oa_location': None, 'sustainable_development_goals': [], 'grants': [], 'datasets': [], 'versions': [], 'referenced_works_count': 29, 'referenced_works': ['https://openalex.org/W1974788729', 'https://openalex.org/W1976697992', 'https://openalex.org/W1982614923', 'https://openalex.org/W1983844160', 'https://openalex.org/W1986369421', 'https://openalex.org/W1988435453', 'https://openalex.org/W2018282312', 'https://openalex.org/W2025010133', 'https://openalex.org/W2031476168', 'https://openalex.org/W2031597075', 'https://openalex.org/W2034734459', 'https://openalex.org/W2038475623', 'https://openalex.org/W2038649405', 'https://openalex.org/W2051092965', 'https://openalex.org/W2056724970', 'https://openalex.org/W2061801246', 'https://openalex.org/W2066696747', 'https://openalex.org/W2067910127', 'https://openalex.org/W2073849751', 'https://openalex.org/W2075107700', 'https://openalex.org/W2077854190', 'https://openalex.org/W2080093592', 'https://openalex.org/W2085853559', 'https://openalex.org/W2089862084', 'https://openalex.org/W2094740671', 'https://openalex.org/W2119790308', 'https://openalex.org/W2148289779', 'https://openalex.org/W2170426276', 'https://openalex.org/W4242239866'], 'related_works': ['https://openalex.org/W4388778533', 'https://openalex.org/W2352537939', 'https://openalex.org/W2165187062', 'https://openalex.org/W2127421218', 'https://openalex.org/W2079491595', 'https://openalex.org/W2074284628', 'https://openalex.org/W2041368477', 'https://openalex.org/W2031597075', 'https://openalex.org/W2028433076', 'https://openalex.org/W2008540511'], 'abstract_inverted_index': {'Polyaniline': [0], 'is': [1], 'doped': [2], 'with': [3, 8, 30], 'an': [4], 'Alq3': [5], 'homologue': [6], 'endowed': [7], 'sulfonic': [9], 'acid': [10], 'functionalities.': [11], 'The': [12], 'design': [13], 'of': [14, 21, 43], 'the': [15, 19, 26, 40, 44], 'dopant,': [16], 'which': [17], 'favors': [18], 'formation': [20], 'a': [22], 'crosslinked': [23], 'network': [24], 'between': [25], 'polymer': [27], 'chains,': [28], 'along': [29], 'its': [31], 'semiconducting': [32], 'electrical': [33], 'properties,': [34], 'highly': [35], 'enhance': [36], 'charge': [37], 'transport': [38], 'inside': [39], 'amorphous': [41], 'phase': [42], 'material': [45], '(see': [46], 'figure).': [47]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W1983599785', 'counts_by_year': [{'year': 2024, 'cited_by_count': 1}, {'year': 2022, 'cited_by_count': 1}, {'year': 2021, 'cited_by_count': 1}, {'year': 2020, 'cited_by_count': 2}, {'year': 2019, 'cited_by_count': 2}, {'year': 2018, 'cited_by_count': 1}, {'year': 2017, 'cited_by_count': 2}, {'year': 2015, 'cited_by_count': 1}, {'year': 2014, 'cited_by_count': 2}, {'year': 2012, 'cited_by_count': 1}], 'updated_date': '2024-12-16T00:08:55.388467', 'created_date': '2016-06-24'}
Publication Information

Basic Information

Access and Citation

AI Researcher Chatbot

Primary Location

Authors

Topics

Keywords

Related Works
