Title: Synthesis and Application of Planar-Chiral Phosphaferrocene-Oxazolines, a New Class of P,N-Ligands
Abstract: The synthesis of several phosphaferrocene-oxazolines, members of a new family of planar-chiral ligands, is described. These bidentate P, N-ligands are applied to enantioselective palladium-catalyzed allylic alkylations, for which it is shown that the planar-chirality of the phosphaferrocene, not the chirality of the oxazoline, determines the stereochemical outcome of the reaction.
Publication Year: 2000
Publication Date: 2000-10-21
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']
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Cited By Count: 75
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