Synthesis and X-ray Structure Determination oftert-Butylhydrazinium Azide andN,N,N-Trimethylhydrazinium Azide

Name: Work Video:
Duration: 3 min 30 s
Description: tert-Butylhydrazinium azide [tBuNH2NH2]+[N3]− (1) was prepared in a high yield reaction from tert-butylhydrazine and HN3. N,N,N-Trimethylhydrazinium azide [NH2N(CH3)3]+[N3]− (2) was prepared from the reaction of silver azide with N,N,N-trimethylhydraziniumiodide. Both were characterized by X-ray structural analysis, IR, Raman, and multinuclear (1H, 13C, 14N) NMR spectroscopy.
T. Habereder; A. Hammerl; G. Höll; Thomas M. Klapötke; Jörg Knizek; Heinrich Nöth
{'id': 'https://openalex.org/W1980229068', 'doi': 'https://doi.org/10.1002/(sici)1099-0682(199905)1999:5<849::aid-ejic849>3.0.co;2-a', 'title': 'Synthesis and X-ray Structure Determination oftert-Butylhydrazinium Azide andN,N,N-Trimethylhydrazinium Azide', 'display_name': 'Synthesis and X-ray Structure Determination oftert-Butylhydrazinium Azide andN,N,N-Trimethylhydrazinium Azide', 'publication_year': 1999, 'publication_date': '1999-05-01', 'ids': {'openalex': 'https://openalex.org/W1980229068', 'doi': 'https://doi.org/10.1002/(sici)1099-0682(199905)1999:5<849::aid-ejic849>3.0.co;2-a', 'mag': '1980229068'}, 'language': 'en', 'primary_location': {'is_oa': False, 'landing_page_url': 'https://doi.org/10.1002/(sici)1099-0682(199905)1999:5<849::aid-ejic849>3.0.co;2-a', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S16435181', 'display_name': 'European Journal of Inorganic Chemistry', 'issn_l': '1434-1948', 'issn': ['1434-1948', '1099-0682'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320595', 'host_organization_name': 'Wiley', 'host_organization_lineage': ['https://openalex.org/P4310320595'], 'host_organization_lineage_names': ['Wiley'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}, 'type': 'article', 'type_crossref': 'journal-article', 'indexed_in': ['crossref'], 'open_access': {'is_oa': False, 'oa_status': 'closed', 'oa_url': None, 'any_repository_has_fulltext': False}, 'authorships': [{'author_position': 'first', 'author': {'id': 'https://openalex.org/A5051504480', 'display_name': 'T. Habereder', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I8204097', 'display_name': 'Ludwig-Maximilians-Universität München', 'ror': 'https://ror.org/05591te55', 'country_code': 'DE', 'type': 'education', 'lineage': ['https://openalex.org/I8204097']}], 'countries': ['DE'], 'is_corresponding': False, 'raw_author_name': 'Tassilo Habereder', 'raw_affiliation_strings': ['Institute of Inorganic Chemistry, University of Munich, Butenandtstraße 5–13 (Haus D), D‐81377 München, Germany Fax: (internat.) 49 (0)89/2180‐7492'], 'affiliations': [{'raw_affiliation_string': 'Institute of Inorganic Chemistry, University of Munich, Butenandtstraße 5–13 (Haus D), D‐81377 München, Germany Fax: (internat.) 49 (0)89/2180‐7492', 'institution_ids': ['https://openalex.org/I8204097']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5043780638', 'display_name': 'A. Hammerl', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I8204097', 'display_name': 'Ludwig-Maximilians-Universität München', 'ror': 'https://ror.org/05591te55', 'country_code': 'DE', 'type': 'education', 'lineage': ['https://openalex.org/I8204097']}], 'countries': ['DE'], 'is_corresponding': False, 'raw_author_name': 'Anton Hammerl', 'raw_affiliation_strings': ['Institute of Inorganic Chemistry, University of Munich, Butenandtstraße 5–13 (Haus D), D‐81377 München, Germany Fax: (internat.) 49 (0)89/2180‐7492'], 'affiliations': [{'raw_affiliation_string': 'Institute of Inorganic Chemistry, University of Munich, Butenandtstraße 5–13 (Haus D), D‐81377 München, Germany Fax: (internat.) 49 (0)89/2180‐7492', 'institution_ids': ['https://openalex.org/I8204097']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5039669221', 'display_name': 'G. Höll', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I4210122827', 'display_name': 'Wehrwissenschaftliche Institut für Schutztechnologien', 'ror': 'https://ror.org/02gfar685', 'country_code': 'DE', 'type': 'facility', 'lineage': ['https://openalex.org/I4210122827', 'https://openalex.org/I4387152969']}], 'countries': ['DE'], 'is_corresponding': False, 'raw_author_name': 'Gerhard Holl', 'raw_affiliation_strings': ['Wehrwissenschaftliches Institut für Werk‐, Explosiv‐ und Betriebsstoffe, D‐53913 Swisstal, Germany'], 'affiliations': [{'raw_affiliation_string': 'Wehrwissenschaftliches Institut für Werk‐, Explosiv‐ und Betriebsstoffe, D‐53913 Swisstal, Germany', 'institution_ids': ['https://openalex.org/I4210122827']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5109041994', 'display_name': 'Thomas M. Klapötke', 'orcid': None}, 'institutions': [], 'countries': [], 'is_corresponding': False, 'raw_author_name': 'Thomas M. Klapötke', 'raw_affiliation_strings': [], 'affiliations': []}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5111858841', 'display_name': 'Jörg Knizek', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I8204097', 'display_name': 'Ludwig-Maximilians-Universität München', 'ror': 'https://ror.org/05591te55', 'country_code': 'DE', 'type': 'education', 'lineage': ['https://openalex.org/I8204097']}], 'countries': ['DE'], 'is_corresponding': False, 'raw_author_name': 'Jörg Knizek', 'raw_affiliation_strings': ['Institute of Inorganic Chemistry, University of Munich, Butenandtstraße 5–13 (Haus D), D‐81377 München, Germany Fax: (internat.) 49 (0)89/2180‐7492'], 'affiliations': [{'raw_affiliation_string': 'Institute of Inorganic Chemistry, University of Munich, Butenandtstraße 5–13 (Haus D), D‐81377 München, Germany Fax: (internat.) 49 (0)89/2180‐7492', 'institution_ids': ['https://openalex.org/I8204097']}]}, {'author_position': 'last', 'author': {'id': 'https://openalex.org/A5085011812', 'display_name': 'Heinrich Nöth', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I8204097', 'display_name': 'Ludwig-Maximilians-Universität München', 'ror': 'https://ror.org/05591te55', 'country_code': 'DE', 'type': 'education', 'lineage': ['https://openalex.org/I8204097']}], 'countries': ['DE'], 'is_corresponding': False, 'raw_author_name': 'Heinrich Nöth', 'raw_affiliation_strings': ['Institute of Inorganic Chemistry, University of Munich, Butenandtstraße 5–13 (Haus D), D‐81377 München, Germany Fax: (internat.) 49 (0)89/2180‐7492'], 'affiliations': [{'raw_affiliation_string': 'Institute of Inorganic Chemistry, University of Munich, Butenandtstraße 5–13 (Haus D), D‐81377 München, Germany Fax: (internat.) 49 (0)89/2180‐7492', 'institution_ids': ['https://openalex.org/I8204097']}]}], 'institution_assertions': [], 'countries_distinct_count': 1, 'institutions_distinct_count': 2, 'corresponding_author_ids': [], 'corresponding_institution_ids': [], 'apc_list': {'value': 3860, 'currency': 'USD', 'value_usd': 3860, 'provenance': 'doaj'}, 'apc_paid': None, 'fwci': 0.607, 'has_fulltext': True, 'fulltext_origin': 'ngrams', 'cited_by_count': 15, 'citation_normalized_percentile': {'value': 0.700093, 'is_in_top_1_percent': False, 'is_in_top_10_percent': False}, 'cited_by_percentile_year': {'min': 81, 'max': 82}, 'biblio': {'volume': '1999', 'issue': '5', 'first_page': '849', 'last_page': '852'}, 'is_retracted': False, 'is_paratext': False, 'primary_topic': {'id': 'https://openalex.org/T13253', 'display_name': 'Chemical Reactions and Mechanisms', 'score': 0.9972, 'subfield': {'id': 'https://openalex.org/subfields/1606', 'display_name': 'Physical and Theoretical Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, 'topics': [{'id': 'https://openalex.org/T13253', 'display_name': 'Chemical Reactions and Mechanisms', 'score': 0.9972, 'subfield': {'id': 'https://openalex.org/subfields/1606', 'display_name': 'Physical and Theoretical Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T11279', 'display_name': 'Lanthanide and Transition Metal Complexes', 'score': 0.9909, 'subfield': {'id': 'https://openalex.org/subfields/2505', 'display_name': 'Materials Chemistry'}, 'field': {'id': 'https://openalex.org/fields/25', 'display_name': 'Materials Science'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T10973', 'display_name': 'Radioactive element chemistry and processing', 'score': 0.99, 'subfield': {'id': 'https://openalex.org/subfields/1604', 'display_name': 'Inorganic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}], 'keywords': [], 'concepts': [{'id': 'https://openalex.org/C2780997848', 'wikidata': 'https://www.wikidata.org/wiki/Q407627', 'display_name': 'Azide', 'level': 2, 'score': 0.9734149}, {'id': 'https://openalex.org/C185592680', 'wikidata': 'https://www.wikidata.org/wiki/Q2329', 'display_name': 'Chemistry', 'level': 0, 'score': 0.92826957}, {'id': 'https://openalex.org/C40003534', 'wikidata': 'https://www.wikidata.org/wiki/Q862228', 'display_name': 'Raman spectroscopy', 'level': 2, 'score': 0.6449238}, {'id': 'https://openalex.org/C134121241', 'wikidata': 'https://www.wikidata.org/wiki/Q899301', 'display_name': 'Yield (engineering)', 'level': 2, 'score': 0.61618775}, {'id': 'https://openalex.org/C2779328170', 'wikidata': 'https://www.wikidata.org/wiki/Q34777', 'display_name': 'X-ray', 'level': 2, 'score': 0.42415878}, {'id': 'https://openalex.org/C66974803', 'wikidata': 'https://www.wikidata.org/wiki/Q10359898', 'display_name': 'Nuclear magnetic resonance spectroscopy', 'level': 2, 'score': 0.42392284}, {'id': 'https://openalex.org/C8010536', 'wikidata': 'https://www.wikidata.org/wiki/Q160398', 'display_name': 'Crystallography', 'level': 1, 'score': 0.33950722}, {'id': 'https://openalex.org/C71240020', 'wikidata': 'https://www.wikidata.org/wiki/Q186011', 'display_name': 'Stereochemistry', 'level': 1, 'score': 0.2169277}, {'id': 'https://openalex.org/C178790620', 'wikidata': 'https://www.wikidata.org/wiki/Q11351', 'display_name': 'Organic chemistry', 'level': 1, 'score': 0.19444591}, {'id': 'https://openalex.org/C191897082', 'wikidata': 'https://www.wikidata.org/wiki/Q11467', 'display_name': 'Metallurgy', 'level': 1, 'score': 0.04826927}, {'id': 'https://openalex.org/C121332964', 'wikidata': 'https://www.wikidata.org/wiki/Q413', 'display_name': 'Physics', 'level': 0, 'score': 0.0}, {'id': 'https://openalex.org/C192562407', 'wikidata': 'https://www.wikidata.org/wiki/Q228736', 'display_name': 'Materials science', 'level': 0, 'score': 0.0}, {'id': 'https://openalex.org/C62520636', 'wikidata': 'https://www.wikidata.org/wiki/Q944', 'display_name': 'Quantum mechanics', 'level': 1, 'score': 0.0}, {'id': 'https://openalex.org/C120665830', 'wikidata': 'https://www.wikidata.org/wiki/Q14620', 'display_name': 'Optics', 'level': 1, 'score': 0.0}], 'mesh': [], 'locations_count': 1, 'locations': [{'is_oa': False, 'landing_page_url': 'https://doi.org/10.1002/(sici)1099-0682(199905)1999:5<849::aid-ejic849>3.0.co;2-a', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S16435181', 'display_name': 'European Journal of Inorganic Chemistry', 'issn_l': '1434-1948', 'issn': ['1434-1948', '1099-0682'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320595', 'host_organization_name': 'Wiley', 'host_organization_lineage': ['https://openalex.org/P4310320595'], 'host_organization_lineage_names': ['Wiley'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}], 'best_oa_location': None, 'sustainable_development_goals': [{'id': 'https://metadata.un.org/sdg/6', 'score': 0.44, 'display_name': 'Clean water and sanitation'}], 'grants': [], 'datasets': [], 'versions': [], 'referenced_works_count': 16, 'referenced_works': ['https://openalex.org/W1586122318', 'https://openalex.org/W1982663864', 'https://openalex.org/W1984976014', 'https://openalex.org/W2028267368', 'https://openalex.org/W2056186542', 'https://openalex.org/W2068238607', 'https://openalex.org/W2081722795', 'https://openalex.org/W2083970216', 'https://openalex.org/W2091079610', 'https://openalex.org/W2102360395', 'https://openalex.org/W2123056007', 'https://openalex.org/W2133114099', 'https://openalex.org/W2162847020', 'https://openalex.org/W2182266687', 'https://openalex.org/W3138615145', 'https://openalex.org/W4300021778'], 'related_works': ['https://openalex.org/W960385439', 'https://openalex.org/W4213082529', 'https://openalex.org/W2148403720', 'https://openalex.org/W2138878738', 'https://openalex.org/W2068483297', 'https://openalex.org/W2065492434', 'https://openalex.org/W2058864804', 'https://openalex.org/W2007615004', 'https://openalex.org/W1975083980', 'https://openalex.org/W1487885362'], 'abstract_inverted_index': {'tert-Butylhydrazinium': [0], 'azide': [1, 16, 26], '[tBuNH2NH2]+[N3]−': [2], '(1)': [3], 'was': [4, 19], 'prepared': [5, 20], 'in': [6], 'a': [7], 'high': [8], 'yield': [9], 'reaction': [10, 23], 'from': [11, 21], 'tert-butylhydrazine': [12], 'and': [13, 38], 'HN3.': [14], 'N,N,N-Trimethylhydrazinium': [15], '[NH2N(CH3)3]+[N3]−': [17], '(2)': [18], 'the': [22], 'of': [24], 'silver': [25], 'with': [27], 'N,N,N-trimethylhydraziniumiodide.': [28], 'Both': [29], 'were': [30], 'characterized': [31], 'by': [32], 'X-ray': [33], 'structural': [34], 'analysis,': [35], 'IR,': [36], 'Raman,': [37], 'multinuclear': [39], '(1H,': [40], '13C,': [41], '14N)': [42], 'NMR': [43], 'spectroscopy.': [44]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W1980229068', 'counts_by_year': [{'year': 2024, 'cited_by_count': 1}, {'year': 2023, 'cited_by_count': 2}, {'year': 2014, 'cited_by_count': 3}, {'year': 2012, 'cited_by_count': 1}], 'updated_date': '2024-12-07T19:10:44.208580', 'created_date': '2016-06-24'}
Publication Information

Basic Information

Access and Citation

AI Researcher Chatbot

Primary Location

Authors

Topics

Keywords

Related Works
