Title: Standard molar enthalpy of formation of crystalline dicarbonylbiscyclopentadienyltitanium(II)
Abstract: The standard (p0 = 0.1 MPa) molar enthalpy of formation, at 298.15 K, of crystalline dicarbonylbiscyclopentadienyltitanium(II), Ti(η-C5H5)2(CO)2, has been derived from the enthalpy of the oxidative reaction of Ti(η-C5H5)2(CO)2 with 9,10-phenanthraquinone in toluene determined by precision solution-reaction calorimetry) as ΔHf0 {Ti(η-C5H5)2(CO)2, cr} = −371.5 ± 12.9 kJ mol−1. A re-evaluation of the TiCO bond enthalpy term and an estimate of the mean bond dissociation enthalpy are also described.
Publication Year: 1990
Publication Date: 1990-09-01
Language: en
Type: article
Indexed In: ['crossref']
Access and Citation
Cited By Count: 3
AI Researcher Chatbot
Get quick answers to your questions about the article from our AI researcher chatbot