Title: Phosphonic Acid‐Modified Barium Titanate Polymer Nanocomposites with High Permittivity and Dielectric Strength
Abstract: Advanced MaterialsVolume 19, Issue 7 p. 1001-1005 Communication Phosphonic Acid-Modified Barium Titanate Polymer Nanocomposites with High Permittivity and Dielectric Strength† P. Kim, P. Kim School of Chemistry and Biochemistry, and Center for Organic Photonics and Electronics, Georgia Institute of Technology, 901 Atlantic Drive, Atlanta, GA 30332 (USA)Search for more papers by this authorS. C. Jones, S. C. Jones School of Chemistry and Biochemistry, and Center for Organic Photonics and Electronics, Georgia Institute of Technology, 901 Atlantic Drive, Atlanta, GA 30332 (USA)Search for more papers by this authorP. J. Hotchkiss, P. J. Hotchkiss School of Chemistry and Biochemistry, and Center for Organic Photonics and Electronics, Georgia Institute of Technology, 901 Atlantic Drive, Atlanta, GA 30332 (USA)Search for more papers by this authorJ. N. Haddock, J. N. Haddock School of Electrical and Computer Engineering, and Center for Organic Photonics and Electronics, Georgia Institute of Technology, 777 Atlantic Drive, Atlanta, GA 30332 (USA)Search for more papers by this authorB. Kippelen, B. Kippelen School of Electrical and Computer Engineering, and Center for Organic Photonics and Electronics, Georgia Institute of Technology, 777 Atlantic Drive, Atlanta, GA 30332 (USA)Search for more papers by this authorS. R. Marder, S. R. Marder [email protected] School of Chemistry and Biochemistry, and Center for Organic Photonics and Electronics, Georgia Institute of Technology, 901 Atlantic Drive, Atlanta, GA 30332 (USA)Search for more papers by this authorJ. W. Perry, J. W. Perry [email protected] School of Chemistry and Biochemistry, and Center for Organic Photonics and Electronics, Georgia Institute of Technology, 901 Atlantic Drive, Atlanta, GA 30332 (USA)Search for more papers by this author P. Kim, P. Kim School of Chemistry and Biochemistry, and Center for Organic Photonics and Electronics, Georgia Institute of Technology, 901 Atlantic Drive, Atlanta, GA 30332 (USA)Search for more papers by this authorS. C. Jones, S. C. Jones School of Chemistry and Biochemistry, and Center for Organic Photonics and Electronics, Georgia Institute of Technology, 901 Atlantic Drive, Atlanta, GA 30332 (USA)Search for more papers by this authorP. J. Hotchkiss, P. J. Hotchkiss School of Chemistry and Biochemistry, and Center for Organic Photonics and Electronics, Georgia Institute of Technology, 901 Atlantic Drive, Atlanta, GA 30332 (USA)Search for more papers by this authorJ. N. Haddock, J. N. Haddock School of Electrical and Computer Engineering, and Center for Organic Photonics and Electronics, Georgia Institute of Technology, 777 Atlantic Drive, Atlanta, GA 30332 (USA)Search for more papers by this authorB. Kippelen, B. Kippelen School of Electrical and Computer Engineering, and Center for Organic Photonics and Electronics, Georgia Institute of Technology, 777 Atlantic Drive, Atlanta, GA 30332 (USA)Search for more papers by this authorS. R. Marder, S. R. Marder [email protected] School of Chemistry and Biochemistry, and Center for Organic Photonics and Electronics, Georgia Institute of Technology, 901 Atlantic Drive, Atlanta, GA 30332 (USA)Search for more papers by this authorJ. W. Perry, J. W. Perry [email protected] School of Chemistry and Biochemistry, and Center for Organic Photonics and Electronics, Georgia Institute of Technology, 901 Atlantic Drive, Atlanta, GA 30332 (USA)Search for more papers by this author First published: 06 March 2007 https://doi.org/10.1002/adma.200602422Citations: 547 † Support of this research by the Office of Naval Research (ONR N00014-03-1-0731) and the STC program (DMR-0120967) and NIRT program (DMR-0454533) of the National Science Foundation is gratefully acknowledged. The authors thank Dr. J. Leisen for SSNMR measurements and Professors S. Kumar, U. H. F. Bunz, C. Jones, N. Kröger, and C. P. Wong for use of equipment in their labs. Supporting Information is available online from Wiley InterScience or from the author. AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Phosphonic acids act as robust surface modifiers on barium titanate (BT) nanoparticles (NPs) (see figure), affording homogeneous, high-volume-fraction composites of such NPs in polymeric hosts by simple solution processing. Pentafluorobenzyl phosphonic acid-modified BT nanocomposite films in poly(vinylidenefluoride-co-hexafluoropropylene) show large relative permittivities and unusually high dielectric breakdown strengths. Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2089/2007/c2422_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. REFERENCES 1 Y. Rao, C. P. Wong, J. Appl. Polym. Sci. 2004, 92, 2228. 10.1002/app.13690 CASWeb of Science®Google Scholar 2 R. Schroeder, L. A. Majewski, M. Grell, Adv. Mater. 2005, 17, 1535. 10.1002/adma.200401398 CASWeb of Science®Google Scholar 3 C. H. Lee, S. H. Hur, Y. C. Shin, J. H. Choi, D. G. Park, K. Kim, Appl. Phys. Lett. 2005, 86, 152908. 10.1063/1.1897431 CASWeb of Science®Google Scholar 4 K. M. Slenes, L. E. Bragg, IEEE Trans. Magn. 2005, 41, 326. 10.1109/TMAG.2004.839291 CASWeb of Science®Google Scholar 5 J. Ihlefeld, B. Laughlin, A. Hunt-Lowery, W. Borland, A. 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Publication Year: 2007
Publication Date: 2007-03-06
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 580
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