Title: Mechanistic pathways in phosphate ester photochemistry
Abstract: Initial bond breaking processes (homolysis vs heterolysis) of phosphate ester photosolvolysis were probed by chemically trapping the reactive intermediates with a tethered 5-hexenyl group. The resulting mechanistic picture is a blend of homolytic and heterolytic pathways, where the heterolytic cleavage is dominant.
Publication Year: 1991
Publication Date: 1991-11-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 1
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