Solubility of Poly(β-hydroxybutyrate) in Supercritical Carbon Dioxide

Name: Work Video:
Duration: 3 min 30 s
Description: The equilibrium solubility of poly(β-hydroxybutyrate) (PHB) in supercritical carbon dioxide was studied. The effects of the main parameters such as pressure, temperature, and solvent density on solubility were determined at temperatures ranging from (308 to 348) K and pressures from (122 to 355) bar. The measured solubility was correlated using the model proposed by Chrastil.
Kianoush Khosravi‐Darani; Ebrahim Vasheghani‐Farahani; Yadollah Yamini; Naader Bahramifar
{'id': 'https://openalex.org/W1968288343', 'doi': 'https://doi.org/10.1021/je020168v', 'title': 'Solubility of Poly(β-hydroxybutyrate) in Supercritical Carbon Dioxide', 'display_name': 'Solubility of Poly(β-hydroxybutyrate) in Supercritical Carbon Dioxide', 'publication_year': 2003, 'publication_date': '2003-06-17', 'ids': {'openalex': 'https://openalex.org/W1968288343', 'doi': 'https://doi.org/10.1021/je020168v', 'mag': '1968288343'}, 'language': 'en', 'primary_location': {'is_oa': False, 'landing_page_url': 'https://doi.org/10.1021/je020168v', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S204459408', 'display_name': 'Journal of Chemical & Engineering Data', 'issn_l': '0021-9568', 'issn': ['0021-9568', '1520-5134'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320006', 'host_organization_name': 'American Chemical Society', 'host_organization_lineage': ['https://openalex.org/P4310320006'], 'host_organization_lineage_names': ['American Chemical Society'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}, 'type': 'article', 'type_crossref': 'journal-article', 'indexed_in': ['crossref'], 'open_access': {'is_oa': False, 'oa_status': 'closed', 'oa_url': None, 'any_repository_has_fulltext': False}, 'authorships': [{'author_position': 'first', 'author': {'id': 'https://openalex.org/A5078574284', 'display_name': 'Kianoush Khosravi‐Darani', 'orcid': 'https://orcid.org/0000-0002-0269-6385'}, 'institutions': [{'id': 'https://openalex.org/I1516879', 'display_name': 'Tarbiat Modares University', 'ror': 'https://ror.org/03mwgfy56', 'country_code': 'IR', 'type': 'education', 'lineage': ['https://openalex.org/I1516879']}], 'countries': ['IR'], 'is_corresponding': False, 'raw_author_name': 'Kianoush Khosravi-Darani', 'raw_affiliation_strings': ['Department of Chemical Engineering, Tarbiat Modarres University, P.O. Box 14115-143, and Department of Chemistry, Tarbiat Modarres University, P.O. Box 14115-175, Tehran, Iran'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemical Engineering, Tarbiat Modarres University, P.O. Box 14115-143, and Department of Chemistry, Tarbiat Modarres University, P.O. Box 14115-175, Tehran, Iran', 'institution_ids': ['https://openalex.org/I1516879']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5021522417', 'display_name': 'Ebrahim Vasheghani‐Farahani', 'orcid': 'https://orcid.org/0000-0002-3802-2104'}, 'institutions': [{'id': 'https://openalex.org/I1516879', 'display_name': 'Tarbiat Modares University', 'ror': 'https://ror.org/03mwgfy56', 'country_code': 'IR', 'type': 'education', 'lineage': ['https://openalex.org/I1516879']}], 'countries': ['IR'], 'is_corresponding': False, 'raw_author_name': 'Ebrahim Vasheghani-Farahani', 'raw_affiliation_strings': ['Department of Chemical Engineering, Tarbiat Modarres University, P.O. Box 14115-143, and Department of Chemistry, Tarbiat Modarres University, P.O. Box 14115-175, Tehran, Iran'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemical Engineering, Tarbiat Modarres University, P.O. Box 14115-143, and Department of Chemistry, Tarbiat Modarres University, P.O. Box 14115-175, Tehran, Iran', 'institution_ids': ['https://openalex.org/I1516879']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5080256942', 'display_name': 'Yadollah Yamini', 'orcid': 'https://orcid.org/0000-0002-2484-9477'}, 'institutions': [{'id': 'https://openalex.org/I1516879', 'display_name': 'Tarbiat Modares University', 'ror': 'https://ror.org/03mwgfy56', 'country_code': 'IR', 'type': 'education', 'lineage': ['https://openalex.org/I1516879']}], 'countries': ['IR'], 'is_corresponding': False, 'raw_author_name': 'Yadollah Yamini', 'raw_affiliation_strings': ['Department of Chemical Engineering, Tarbiat Modarres University, P.O. Box 14115-143, and Department of Chemistry, Tarbiat Modarres University, P.O. Box 14115-175, Tehran, Iran'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemical Engineering, Tarbiat Modarres University, P.O. Box 14115-143, and Department of Chemistry, Tarbiat Modarres University, P.O. Box 14115-175, Tehran, Iran', 'institution_ids': ['https://openalex.org/I1516879']}]}, {'author_position': 'last', 'author': {'id': 'https://openalex.org/A5037282958', 'display_name': 'Naader Bahramifar', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I1516879', 'display_name': 'Tarbiat Modares University', 'ror': 'https://ror.org/03mwgfy56', 'country_code': 'IR', 'type': 'education', 'lineage': ['https://openalex.org/I1516879']}], 'countries': ['IR'], 'is_corresponding': False, 'raw_author_name': 'Naader Bahramifar', 'raw_affiliation_strings': ['Department of Chemical Engineering, Tarbiat Modarres University, P.O. Box 14115-143, and Department of Chemistry, Tarbiat Modarres University, P.O. Box 14115-175, Tehran, Iran'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemical Engineering, Tarbiat Modarres University, P.O. Box 14115-143, and Department of Chemistry, Tarbiat Modarres University, P.O. Box 14115-175, Tehran, Iran', 'institution_ids': ['https://openalex.org/I1516879']}]}], 'institution_assertions': [], 'countries_distinct_count': 1, 'institutions_distinct_count': 1, 'corresponding_author_ids': [], 'corresponding_institution_ids': [], 'apc_list': None, 'apc_paid': None, 'fwci': 1.358, 'has_fulltext': False, 'cited_by_count': 41, 'citation_normalized_percentile': {'value': 0.907489, 'is_in_top_1_percent': False, 'is_in_top_10_percent': True}, 'cited_by_percentile_year': {'min': 91, 'max': 92}, 'biblio': {'volume': '48', 'issue': '4', 'first_page': '860', 'last_page': '863'}, 'is_retracted': False, 'is_paratext': False, 'primary_topic': {'id': 'https://openalex.org/T10402', 'display_name': 'Phase Equilibria and Thermodynamics', 'score': 0.9993, 'subfield': {'id': 'https://openalex.org/subfields/2204', 'display_name': 'Biomedical Engineering'}, 'field': {'id': 'https://openalex.org/fields/22', 'display_name': 'Engineering'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, 'topics': [{'id': 'https://openalex.org/T10402', 'display_name': 'Phase Equilibria and Thermodynamics', 'score': 0.9993, 'subfield': {'id': 'https://openalex.org/subfields/2204', 'display_name': 'Biomedical Engineering'}, 'field': {'id': 'https://openalex.org/fields/22', 'display_name': 'Engineering'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T12628', 'display_name': 'Polymer Foaming and Composites', 'score': 0.9984, 'subfield': {'id': 'https://openalex.org/subfields/2507', 'display_name': 'Polymers and Plastics'}, 'field': {'id': 'https://openalex.org/fields/25', 'display_name': 'Materials Science'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T11593', 'display_name': 'Carbon dioxide utilization in catalysis', 'score': 0.9981, 'subfield': {'id': 'https://openalex.org/subfields/1508', 'display_name': 'Process Chemistry and Technology'}, 'field': {'id': 'https://openalex.org/fields/15', 'display_name': 'Chemical Engineering'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}], 'keywords': [{'id': 'https://openalex.org/keywords/supercritical-carbon-dioxide', 'display_name': 'Supercritical Carbon Dioxide', 'score': 0.89836866}, {'id': 'https://openalex.org/keywords/bar', 'display_name': 'Bar (unit)', 'score': 0.5534202}, {'id': 'https://openalex.org/keywords/hildebrand-solubility-parameter', 'display_name': 'Hildebrand solubility parameter', 'score': 0.4172664}], 'concepts': [{'id': 'https://openalex.org/C155574463', 'wikidata': 'https://www.wikidata.org/wiki/Q170731', 'display_name': 'Solubility', 'level': 2, 'score': 0.9479196}, {'id': 'https://openalex.org/C185592680', 'wikidata': 'https://www.wikidata.org/wiki/Q2329', 'display_name': 'Chemistry', 'level': 0, 'score': 0.90687513}, {'id': 'https://openalex.org/C134458231', 'wikidata': 'https://www.wikidata.org/wiki/Q332582', 'display_name': 'Supercritical carbon dioxide', 'level': 3, 'score': 0.89836866}, {'id': 'https://openalex.org/C118419359', 'wikidata': 'https://www.wikidata.org/wiki/Q682585', 'display_name': 'Supercritical fluid', 'level': 2, 'score': 0.7563946}, {'id': 'https://openalex.org/C2780471494', 'wikidata': 'https://www.wikidata.org/wiki/Q146505', 'display_name': 'Solvent', 'level': 2, 'score': 0.6509359}, {'id': 'https://openalex.org/C530467964', 'wikidata': 'https://www.wikidata.org/wiki/Q1997', 'display_name': 'Carbon dioxide', 'level': 2, 'score': 0.63638556}, {'id': 'https://openalex.org/C188721877', 'wikidata': 'https://www.wikidata.org/wiki/Q103510', 'display_name': 'Bar (unit)', 'level': 2, 'score': 0.5534202}, {'id': 'https://openalex.org/C100293340', 'wikidata': 'https://www.wikidata.org/wiki/Q3895235', 'display_name': 'Hildebrand solubility parameter', 'level': 3, 'score': 0.4172664}, {'id': 'https://openalex.org/C97355855', 'wikidata': 'https://www.wikidata.org/wiki/Q11473', 'display_name': 'Thermodynamics', 'level': 1, 'score': 0.37347853}, {'id': 'https://openalex.org/C178790620', 'wikidata': 'https://www.wikidata.org/wiki/Q11351', 'display_name': 'Organic chemistry', 'level': 1, 'score': 0.37295407}, {'id': 'https://openalex.org/C121332964', 'wikidata': 'https://www.wikidata.org/wiki/Q413', 'display_name': 'Physics', 'level': 0, 'score': 0.0}, {'id': 'https://openalex.org/C153294291', 'wikidata': 'https://www.wikidata.org/wiki/Q25261', 'display_name': 'Meteorology', 'level': 1, 'score': 0.0}], 'mesh': [], 'locations_count': 1, 'locations': [{'is_oa': False, 'landing_page_url': 'https://doi.org/10.1021/je020168v', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S204459408', 'display_name': 'Journal of Chemical & Engineering Data', 'issn_l': '0021-9568', 'issn': ['0021-9568', '1520-5134'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320006', 'host_organization_name': 'American Chemical Society', 'host_organization_lineage': ['https://openalex.org/P4310320006'], 'host_organization_lineage_names': ['American Chemical Society'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}], 'best_oa_location': None, 'sustainable_development_goals': [{'score': 0.68, 'display_name': 'Clean water and sanitation', 'id': 'https://metadata.un.org/sdg/6'}], 'grants': [], 'datasets': [], 'versions': [], 'referenced_works_count': 17, 'referenced_works': ['https://openalex.org/W1503363495', 'https://openalex.org/W1533868191', 'https://openalex.org/W1937279395', 'https://openalex.org/W1972922040', 'https://openalex.org/W1996369603', 'https://openalex.org/W1997204384', 'https://openalex.org/W2005677007', 'https://openalex.org/W2030102318', 'https://openalex.org/W2050397787', 'https://openalex.org/W2058695418', 'https://openalex.org/W2066274443', 'https://openalex.org/W2066754179', 'https://openalex.org/W2068728652', 'https://openalex.org/W2077778604', 'https://openalex.org/W2081487852', 'https://openalex.org/W2951886133', 'https://openalex.org/W3157512479'], 'related_works': ['https://openalex.org/W930150328', 'https://openalex.org/W4362664378', 'https://openalex.org/W2763312086', 'https://openalex.org/W2352541201', 'https://openalex.org/W2081591825', 'https://openalex.org/W2051956325', 'https://openalex.org/W2034346728', 'https://openalex.org/W2031034711', 'https://openalex.org/W1969032323', 'https://openalex.org/W1963653379'], 'abstract_inverted_index': {'The': [0, 12, 44], 'equilibrium': [1], 'solubility': [2, 26, 46], 'of': [3, 14], 'poly(β-hydroxybutyrate)': [4], '(PHB)': [5], 'in': [6], 'supercritical': [7], 'carbon': [8], 'dioxide': [9], 'was': [10, 47], 'studied.': [11], 'effects': [13], 'the': [15, 50], 'main': [16], 'parameters': [17], 'such': [18], 'as': [19], 'pressure,': [20], 'temperature,': [21], 'and': [22, 37], 'solvent': [23], 'density': [24], 'on': [25], 'were': [27], 'determined': [28], 'at': [29], 'temperatures': [30], 'ranging': [31], 'from': [32, 39], '(308': [33], 'to': [34, 41], '348)': [35], 'K': [36], 'pressures': [38], '(122': [40], '355)': [42], 'bar.': [43], 'measured': [45], 'correlated': [48], 'using': [49], 'model': [51], 'proposed': [52], 'by': [53], 'Chrastil.': [54]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W1968288343', 'counts_by_year': [{'year': 2023, 'cited_by_count': 4}, {'year': 2022, 'cited_by_count': 2}, {'year': 2021, 'cited_by_count': 3}, {'year': 2020, 'cited_by_count': 5}, {'year': 2019, 'cited_by_count': 4}, {'year': 2017, 'cited_by_count': 1}, {'year': 2016, 'cited_by_count': 1}, {'year': 2015, 'cited_by_count': 3}, {'year': 2014, 'cited_by_count': 2}, {'year': 2013, 'cited_by_count': 1}, {'year': 2012, 'cited_by_count': 2}], 'updated_date': '2024-12-11T06:19:48.500198', 'created_date': '2016-06-24'}
Publication Information

Basic Information

Access and Citation

AI Researcher Chatbot

Primary Location

Authors

Topics

Keywords

Related Works
