Title: Deuterium kinetic isotope effect in β-elimination from (p-acetylphenethyl)dimethylsulphonium bromide. The influence of added dimethyl sulphoxide
Abstract: The effect of added dimethyl sulphoxide (Me2SO) on the primary deuterium kinetic isotope effect for NaOH-catalysed β-elimination from (p-acetylphenethyl)dimethylsulphonium bromide has been measured over the range 6–70 mol %. Despite the large increase in reaction rate, no significant maximum in the isotope effect was observed. Substituent induced changes in k2H/k2D are shown to be larger than those caused by addition of Me2SO, despite the large difference in relative rates.
Publication Year: 1976
Publication Date: 1976-01-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 3
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