Title: Supramolecular Assemblies of 1,2-Dicarbadodecaborane(12) with Bowl-Shaped Calix[5]arene
Abstract: European Journal of Inorganic ChemistryVolume 1999, Issue 1 p. 195-200 Full Paper Supramolecular Assemblies of 1,2-Dicarbadodecaborane(12) with Bowl-Shaped Calix[5]arene Michaele J. Hardie, Michaele J. Hardie Department of Chemistry, Monash University, Clayton, Melbourne, Victoria 3168, AustraliaSearch for more papers by this authorColin L. Raston, Colin L. RastonSearch for more papers by this author Michaele J. Hardie, Michaele J. Hardie Department of Chemistry, Monash University, Clayton, Melbourne, Victoria 3168, AustraliaSearch for more papers by this authorColin L. Raston, Colin L. RastonSearch for more papers by this author First published: 23 December 1998 https://doi.org/10.1002/(SICI)1099-0682(199901)1999:1<195::AID-EJIC195>3.0.CO;2-DCitations: 53AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Abstract Treatment of globular 1,2-dicarbadodecaborane(12) (o-carborane) 1 with the bowl-shaped container molecule calix[5]arene 2 affords either the crystalline 1:1 or 1:2 host-guest complexes (o-carborane)(calix[5]arene)(CH2Cl2) 3, (o-carborane)(calix[5]arene)(toluene) 4 and (o-carborane)(calix[5]arene)2(CH2Cl2)0.55. The three complexes show a remarkable range of different supramolecular interplay beyond the common structural unit, a ball-and-socket nano-structure or supermolecule [(o-carborane)∩(calix[5]arene)]. Complex 3 forms dimeric [(o-carborane)∩(calix[5]arene)]2 units, and 5 has an additional edge on interaction between the supermolecule and a secondary calix[5]arene host. References 1 J. Plesek, Chem. Rev. 1992, 92, 269. 2 X. Yang, W. Jiang, C. B. Knobler, M. F. Hawthorne, J. Am. Chem. Soc. 1992, 114, 9717; J. Müller, K. Base, T. F. Magnera, J. Michel, J. Am. Chem. Soc. 1992, 114, 9721; W. 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Publication Year: 1999
Publication Date: 1999-01-01
Language: en
Type: article
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