Title: Regularities of initiation of oxidation of cumene and polymerization of styrene by 2,2'-azobisisobutyronitrile
Abstract: This paper determines the kinetic parameters of the initiation of the oxidation of cumens and polymerization of styrene by using 2,2'-azobisisobutyronitrile (AIBN) as the initiator. The rate of initiation is practically independent of the nature of the aliphatic alcohols (methanol to decanol) and the efficiency of AIBN in this series decreases. The activation energy of the initiation for the two processes in emulsions is 12-16 kJ/mole higher than in a homogeneous system.
Publication Year: 1986
Publication Date: 1986-03-01
Language: en
Type: article
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