Controlled generation of highly saddled (porphyrinato)iron(<scp>iii</scp>) iodide, tri-iodide and one-electron oxidized complexes

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Duration: 3 min 30 s
Description: Three iron(<sc>iii</sc>) porphyrinato complexes have been isolated selectively just by varying the iodine concentration, which eventually form the admixed-intermediate (iodo complex), pure intermediate (tri-iodide complex) and high-spin (1e-oxidized complex) states of iron where iodide and/or tri-iodide were used as axial ligands.
Dipankar Sahoo; Sankar Prasad Rath
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