Title: Neutral Hexacoordinate Silicon(IV) Complexes with a <i>Si</i>O<sub>4</sub>NC or <i>Si</i>O<sub>3</sub>N<sub>2</sub>C Skeleton and Neutral Pentacoordinate Silicon(IV) Complexes Containing a Trianionic Tetradentate <i>O</i>,<i>N</i>,<i>O</i>,<i>O</i> Ligand
Abstract:Abstract A series of neutral hexacoordinate silicon(IV) complexes with a Si O 4 NC or Si O 3 N 2 C skeleton was synthesized. Additionally, two neutral pentacoordinate silicon(IV) complexes with a Si O...Abstract A series of neutral hexacoordinate silicon(IV) complexes with a Si O 4 NC or Si O 3 N 2 C skeleton was synthesized. Additionally, two neutral pentacoordinate silicon(IV) complexes with a Si O 3 NC skeleton were synthesized. All compounds studied were structurally characterized by multinuclear NMR spectroscopy in the solid state and in solution and by single‐crystal X‐ray diffraction. The hexacoordinate compounds studied contain a tridentate dianionic O , N , O or N , N , O ligand, a phenyl ligand, and a symmetrically substituted derivative of an acetylacetonato ligand of the formula type RC(O)–CH=C(OSiMe 3 )R (R = Me, Ph, CF 3 ). The two pentacoordinate complexes contain a tetradentate trianionic O , N , O , O ligand and a phenyl ligand.Read More
Publication Year: 2013
Publication Date: 2013-12-18
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 16
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