Abstract: This chapter contains sections titled: Ziegler–Natta Catalysts in Polyolefin Synthesis Introduction Ziegler–Natta Catalysts for Polypropylene Third-Generation MgCl2-supported Catalysts Fourth-Generation MgCl2-supported Catalysts Fifth-Generation MgCl2-supported Catalysts New Developments Mechanistic Aspects Ziegler Catalysts in Polyethylene Ideal Catalysts? Ball-milled MgCl2-based Ziegler Catalysts MgCl2-Titanium Catalysts on Silica Precipitated and Supported MgCl2-based Catalysts Spray-dried MgCl2-Titanium Catalysts General Polymerization Behavior of the MgCl2-Titanium-based Ziegler Catalysts Models for Chemical Composition Distribution and Comonomer Drift Vanadium-based Ziegler Catalysts Concluding Remarks Chromium Polymerization Catalysts: Still Alive in Polyethylene Production Introduction The Chromium Catalyst System Activation of the Chromium Catalyst Polymerization Mechanism Chromium Catalyst Performance The Effect of Carrier Material and Calcination Temperature Effect of Polymerization Temperature Effect of Hydrogen/Hydrogen Sensitivity Summary References
Publication Year: 2008
Publication Date: 2008-02-20
Language: en
Type: other
Indexed In: ['crossref']
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Cited By Count: 4
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