Title: Synthesis and Crystal Structures of Two Isostructural Cobalt(III) Complexes [Co(C<sub>15</sub>H<sub>21</sub>N<sub>2</sub>O)(C<sub>8</sub>H<sub>7</sub>O<sub>2</sub>)(N<sub>3</sub>)] and [Co(C<sub>15</sub>H<sub>21</sub>N<sub>2</sub>O)(C<sub>8</sub>H<sub>7</sub>O<sub>2</sub>)(NCS)]
Abstract: Two isostructural mononuclear cobalt(III) complexes, [Co(C15H21N2O)(C8H7O2)(N3)] (1) and [Co(C15H21N2O) (C8H7O2)(NCS)] (2), were synthesized and characterized by elemental analysis, IR spectra, and X-ray single crystal structure determination. X-ray structural analysis indicates that both complexes crystallizing in the monoclinic space group P21/c, with a = 13.190(2) Å, b = 12.842(2) Å, c = 18.428(2) Å, β = 134.040(2)°, V = 2243.9(5) Å3, Z = 4 for 1, and a = 8.1284(8) Å, b = 15.6112(15) Å, c = 18.9260(17) Å, β = 106.060(3)°, V = 2307.9(4) Å3, Z = 4 for 2. The Co atom in each complex is coordinated by one Schiff base ligand, one 2-acetylphenolate ligand, and one pseudohalide ligand (N3 for 1 and NCS for 2), forming an octahedral geometry.
Publication Year: 2011
Publication Date: 2011-05-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 2
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