Title: One-Component Catalysts for Polymerization of Olefins
Abstract: One-component catalysts, being simpler in composition, may be a convenient object for the study of the detailed mechanism of catalytic polymerization. This chapter shows recent results of the study of one-component catalysts of olefin polymerization. The study of catalytic polymerization of olefins performed up to the present time is certain to hold a particular influence over the progress of the concepts of the "coordination" mechanism of heterogeneous catalysis. With such an approach, the elementary acts of catalytic reaction are considered to proceed in the coordination sphere of one ion of the transition element and, to a first approximation, the collective features of solids are not taken into account. In catalytic polymerization the possibility arises of determining the absolute values of the rate constants of individual reactions composing the total process. The urgent problem in studying catalytic polymerization is still to obtain more detailed data on the structure of the propagation centers and the mechanism of their formation.
Publication Year: 1975
Publication Date: 1975-01-01
Language: en
Type: book-chapter
Indexed In: ['crossref']
Access and Citation
Cited By Count: 104
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