Title: Asymmetric Additions to α,β-Unsaturated Acyl Phosphonates
Abstract: Jørgensen and co-workers demonstrated the potential of unsaturated acyl phosphonates 4 as hydrogen-bond acceptors in enantioselective organocatalysis. By employing chiral thioureas 1 and 2 or squaramide 3 as catalysts, with different carbon-based nucleophiles (5-7), products 8-10 were obtained in moderate to good yields and high enantioselectivity.
Publication Year: 2010
Publication Date: 2010-03-22
Language: en
Type: article
Indexed In: ['crossref']
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