Title: Synthesis,Crystal Structure and Properties of the Zinc(II) Complex with o-Acetamidobenzoic Acid and 1,10-Phenanthroline
Abstract: The title complex has been synthesized with o-acetamidobenzoic acid and 1,10-phenanthroline(phen) in the solvent mixture of water and methanol.It crystallizes(C66H50N10O15Cl2Zn2,Mr=1 424.80),triclinic,space group P1 with a=1.181 6(6) nm,b=1.635 6(8) nm,c=1.752 2(9) nm,α=95.733(9)°,β=93.083(8)°,γ=109.212(8)°,V=3.168(3) nm3,Dc=1.494 g·cm-3,Z=2,F(000)=1 460,R1=0.048 2,wR2=0.098 3.The crystal structure shows that the zinc atom is coordinated with two oxygen atoms from one o-acetamidobenzoic acids molecules,four nitrogen atoms from two 1,10-phenanthroline molecules,forming a distorted octahedral coordination geometry.TG analysis,spectrum property and the cyclic voltammetric behavior of the complex was investigated.CCDC: 833353.
Publication Year: 2011
Publication Date: 2011-01-01
Language: en
Type: article
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