Title: Synthesis and Crystal Structure of a Novel Organic-Inorganic Hybrid Polyoxometalate Complex
Abstract: A novel polyoxometalate [Fe(phen)3]2(PMo10VⅤ3VⅣO44)·DMF has been synthesized by Hydrothermal method and characterized by single-crystal X-ray diffraction,IR,TG-DTA and XPS.The results indicate that the structure of the title compound consists of(PMo10VⅤ3VⅣO44)4-heteropolyoxoanion,[Fe(phen)3]4+ fragments and DMF molecules.The title compound formed the 3D supramolecular structure via intermolecular hydrogen-bonding interactions.The title compound crystallized in the triclinic,space group P1 with a=1.413 41(4) nm,b=1.835 09(6) nm,c=1.967 63(7) nm,α=83.225 0(10)°,β=69.787 0(10)°,γ=87.021 0(10)°,V=4.755 4(3) nm3,Z=1,Rgt(F) =0.045 9,ωRref(F2) =0.107 9,S=1.016.
Publication Year: 2010
Publication Date: 2010-01-01
Language: en
Type: article
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