Title: Synthesis and Characterization of an Organic-Inorganic Hybrid Compound Templated by Keggin Anions
Abstract: A new compound [Mo2MnⅣ2(OH)O8(bpy)10][PMo12O40] has been synthesized under hydrothermal conditions and characterized by element analysis,single-crystal X-ray diffraction,IR,TG analysis.Single-crystal X-ray structural analysis reveals that the compound crystallizes in the triclinic system,space group P-1,a=11.123(2),b=12.278(3),c=16.239(4),α=106.516(3)°,β=94.784(3)°,γ=90.302(3)°,V=2117.8(8)3,Z=1,F(000)=1538,R1=0.0572,wR2=0.2415.The basic structural unit of the compound is composed of a metal-oxide-based organic-inorganic hybrid host [Mo2MnⅣ2(OH)O8(bpy)10]3+ and a α-Keggin anion [PMo12O40]3-.Its electrocatalytic properties investigated.
Publication Year: 2010
Publication Date: 2010-01-01
Language: en
Type: article
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