Title: Synthesis,Crystal Structure and Fluorescent Properties of[Cd_2(BHP)_2(2,6-pda)_2(H_2O)_2]·H_2O
Abstract: A binuclear complex [Cd2(BHP)2(2,6-pda)2(H2O)2]·H2O with mixed ligands was synthesized from the solvothermal reaction(BHP=pyridine-2,6-dicarbohydrazide and 2,6-H2pda=pyridine-2,6-dicarboxylic acid) and it is characterized by IR and elemental analyses.The results of single-crystal X-ray diffraction analysis show that the title complex crystallizes in the triclinic space group Pī with a=0.999 70(13) nm,b=1.038 00(15) nm,c=1.077 40(16) nm,α=115.601(3)°,β=110.510(3)°,γ=98.416(2)°,V=0.883 7(2) nm3,Z=1.In the title complex,each Cd(Ⅱ) ion is seven-coordinated in distorted pentagonal bipyramidal geometry.Three-dimensional supramolecular is formed by hydrogen bonding interaction in the title complex.Fluorescent properties of the title complex was investigated.
Publication Year: 2012
Publication Date: 2012-01-01
Language: en
Type: article
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