Title: Antagonism between Extreme Negative Linear Compression and Spin Crossover in [Fe(dpp)<sub>2</sub>(NCS)<sub>2</sub>]⋅py
Abstract: Angewandte Chemie International EditionVolume 51, Issue 16 p. 3910-3914 Communication Antagonism between Extreme Negative Linear Compression and Spin Crossover in [Fe(dpp)2(NCS)2]⋅py† Dr. Helena J. Shepherd, Dr. Helena J. Shepherd Laboratoire de Chimie de Coordination, CNRS UPR-8241 Université de Toulouse, UPS, INP, Toulouse (France) CNRS, ICMCB, UPR 9048, 33600 Pessac (France) Univ. Bordeaux, ICMCB, UPR 9048, 33600 Pessac (France)Search for more papers by this authorTatiana Palamarciuc, Tatiana Palamarciuc CNRS, ICMCB, UPR 9048, 33600 Pessac (France) Univ. Bordeaux, ICMCB, UPR 9048, 33600 Pessac (France)Search for more papers by this authorDr. Patrick Rosa, Dr. Patrick Rosa CNRS, ICMCB, UPR 9048, 33600 Pessac (France) Univ. Bordeaux, ICMCB, UPR 9048, 33600 Pessac (France)Search for more papers by this authorProf. Philippe Guionneau, Corresponding Author Prof. Philippe Guionneau [email protected] CNRS, ICMCB, UPR 9048, 33600 Pessac (France) Univ. Bordeaux, ICMCB, UPR 9048, 33600 Pessac (France) Philippe Guionneau, CNRS, ICMCB, UPR 9048, 33600 Pessac (France) Gábor Molnár, Laboratoire de Chimie de Coordination, CNRS UPR-8241Search for more papers by this authorDr. Gábor Molnár, Corresponding Author Dr. Gábor Molnár [email protected] Laboratoire de Chimie de Coordination, CNRS UPR-8241 Université de Toulouse, UPS, INP, Toulouse (France) Philippe Guionneau, CNRS, ICMCB, UPR 9048, 33600 Pessac (France) Gábor Molnár, Laboratoire de Chimie de Coordination, CNRS UPR-8241Search for more papers by this authorDr. Jean-François Létard, Dr. Jean-François Létard CNRS, ICMCB, UPR 9048, 33600 Pessac (France) Univ. Bordeaux, ICMCB, UPR 9048, 33600 Pessac (France)Search for more papers by this authorDr. Azzedine Bousseksou, Dr. Azzedine Bousseksou Laboratoire de Chimie de Coordination, CNRS UPR-8241 Université de Toulouse, UPS, INP, Toulouse (France)Search for more papers by this author Dr. Helena J. Shepherd, Dr. Helena J. Shepherd Laboratoire de Chimie de Coordination, CNRS UPR-8241 Université de Toulouse, UPS, INP, Toulouse (France) CNRS, ICMCB, UPR 9048, 33600 Pessac (France) Univ. Bordeaux, ICMCB, UPR 9048, 33600 Pessac (France)Search for more papers by this authorTatiana Palamarciuc, Tatiana Palamarciuc CNRS, ICMCB, UPR 9048, 33600 Pessac (France) Univ. Bordeaux, ICMCB, UPR 9048, 33600 Pessac (France)Search for more papers by this authorDr. Patrick Rosa, Dr. Patrick Rosa CNRS, ICMCB, UPR 9048, 33600 Pessac (France) Univ. Bordeaux, ICMCB, UPR 9048, 33600 Pessac (France)Search for more papers by this authorProf. Philippe Guionneau, Corresponding Author Prof. Philippe Guionneau [email protected] CNRS, ICMCB, UPR 9048, 33600 Pessac (France) Univ. Bordeaux, ICMCB, UPR 9048, 33600 Pessac (France) Philippe Guionneau, CNRS, ICMCB, UPR 9048, 33600 Pessac (France) Gábor Molnár, Laboratoire de Chimie de Coordination, CNRS UPR-8241Search for more papers by this authorDr. Gábor Molnár, Corresponding Author Dr. Gábor Molnár [email protected] Laboratoire de Chimie de Coordination, CNRS UPR-8241 Université de Toulouse, UPS, INP, Toulouse (France) Philippe Guionneau, CNRS, ICMCB, UPR 9048, 33600 Pessac (France) Gábor Molnár, Laboratoire de Chimie de Coordination, CNRS UPR-8241Search for more papers by this authorDr. Jean-François Létard, Dr. Jean-François Létard CNRS, ICMCB, UPR 9048, 33600 Pessac (France) Univ. Bordeaux, ICMCB, UPR 9048, 33600 Pessac (France)Search for more papers by this authorDr. Azzedine Bousseksou, Dr. Azzedine Bousseksou Laboratoire de Chimie de Coordination, CNRS UPR-8241 Université de Toulouse, UPS, INP, Toulouse (France)Search for more papers by this author First published: 08 March 2012 https://doi.org/10.1002/anie.201108919Citations: 94 † Financial support was provided by the ANR Project SCOOP (ANR-08-JCJC-0049-01) We are grateful to A. Filhol for the FORTRAN source code of the DEFORM program. dpp=dipyrido[3,2-a:2′3′-c]phenazine. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Graphical Abstract A scissor-like geometric mechanism is responsible for the strongest negative linear compression effect yet observed in a molecular material, [Fe(dpp)2(NCS)2]⋅py (see picture; dpp=dipyrido[3,2-a:2′3′-c]phenazine), C gray, N blue, S yellow, Fe red). The same mechanism is also responsible for suppressing the high-spin to low-spin transition under pressure. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description anie_201108919_sm_miscellaneous_information.pdf741 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume51, Issue16April 16, 2012Pages 3910-3914 RelatedInformation
Publication Year: 2012
Publication Date: 2012-03-08
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']
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Cited By Count: 110
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