Title: Assembly of Helicene‐Capped N,P,N,P,N‐Helicands within Cu<sup>I</sup> Helicates: Impacting Chiroptical Properties by Ligand–Ligand Charge Transfer
Abstract: Angewandte Chemie International EditionVolume 52, Issue 7 p. 1968-1972 Communication Assembly of Helicene-Capped N,P,N,P,N-Helicands within CuI Helicates: Impacting Chiroptical Properties by Ligand–Ligand Charge Transfer† Dr. Volodimir Vreshch, Dr. Volodimir Vreshch Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France)Search for more papers by this authorMehdi El Sayed Moussa, Mehdi El Sayed Moussa Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France)Search for more papers by this authorDr. Brigitte Nohra, Dr. Brigitte Nohra Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France)Search for more papers by this authorDr. Monika Srebro, Dr. Monika Srebro Department of Chemistry, University at Buffalo, State University of New York, Buffalo, NY 14260 (USA) Department of Theoretical Chemistry, Faculty of Chemistry, Jagiellonian University, 30-060 Krakow (Poland)Search for more papers by this authorDr. Nicolas Vanthuyne, Dr. Nicolas Vanthuyne Chirosciences, UMR 7313, Stéréochimie Dynamique et Chiralité, Aix-Marseille University, 13397 Marseille (France)Search for more papers by this authorProf. Christian Roussel, Prof. Christian Roussel Chirosciences, UMR 7313, Stéréochimie Dynamique et Chiralité, Aix-Marseille University, 13397 Marseille (France)Search for more papers by this authorProf. Jochen Autschbach, Corresponding Author Prof. Jochen Autschbach [email protected] Department of Chemistry, University at Buffalo, State University of New York, Buffalo, NY 14260 (USA) Department of Theoretical Chemistry, Faculty of Chemistry, Jagiellonian University, 30-060 Krakow (Poland) Jochen Autschbach, Department of Chemistry, University at Buffalo, State University of New York, Buffalo, NY 14260 (USA) Jeanne Crassous, Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France) Christophe Lescop, Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France) Régis Réau, Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France)Search for more papers by this authorDr. Jeanne Crassous, Corresponding Author Dr. Jeanne Crassous [email protected] Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France) Jochen Autschbach, Department of Chemistry, University at Buffalo, State University of New York, Buffalo, NY 14260 (USA) Jeanne Crassous, Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France) Christophe Lescop, Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France) Régis Réau, Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France)Search for more papers by this authorDr. Christophe Lescop, Corresponding Author Dr. Christophe Lescop [email protected] Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France) Jochen Autschbach, Department of Chemistry, University at Buffalo, State University of New York, Buffalo, NY 14260 (USA) Jeanne Crassous, Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France) Christophe Lescop, Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France) Régis Réau, Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France)Search for more papers by this authorProf. Régis Réau, Corresponding Author Prof. Régis Réau [email protected] Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France) Jochen Autschbach, Department of Chemistry, University at Buffalo, State University of New York, Buffalo, NY 14260 (USA) Jeanne Crassous, Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France) Christophe Lescop, Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France) Régis Réau, Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France)Search for more papers by this author Dr. Volodimir Vreshch, Dr. Volodimir Vreshch Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France)Search for more papers by this authorMehdi El Sayed Moussa, Mehdi El Sayed Moussa Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France)Search for more papers by this authorDr. Brigitte Nohra, Dr. Brigitte Nohra Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France)Search for more papers by this authorDr. Monika Srebro, Dr. Monika Srebro Department of Chemistry, University at Buffalo, State University of New York, Buffalo, NY 14260 (USA) Department of Theoretical Chemistry, Faculty of Chemistry, Jagiellonian University, 30-060 Krakow (Poland)Search for more papers by this authorDr. Nicolas Vanthuyne, Dr. Nicolas Vanthuyne Chirosciences, UMR 7313, Stéréochimie Dynamique et Chiralité, Aix-Marseille University, 13397 Marseille (France)Search for more papers by this authorProf. Christian Roussel, Prof. Christian Roussel Chirosciences, UMR 7313, Stéréochimie Dynamique et Chiralité, Aix-Marseille University, 13397 Marseille (France)Search for more papers by this authorProf. Jochen Autschbach, Corresponding Author Prof. Jochen Autschbach [email protected] Department of Chemistry, University at Buffalo, State University of New York, Buffalo, NY 14260 (USA) Department of Theoretical Chemistry, Faculty of Chemistry, Jagiellonian University, 30-060 Krakow (Poland) Jochen Autschbach, Department of Chemistry, University at Buffalo, State University of New York, Buffalo, NY 14260 (USA) Jeanne Crassous, Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France) Christophe Lescop, Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France) Régis Réau, Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France)Search for more papers by this authorDr. Jeanne Crassous, Corresponding Author Dr. Jeanne Crassous [email protected] Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France) Jochen Autschbach, Department of Chemistry, University at Buffalo, State University of New York, Buffalo, NY 14260 (USA) Jeanne Crassous, Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France) Christophe Lescop, Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France) Régis Réau, Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France)Search for more papers by this authorDr. Christophe Lescop, Corresponding Author Dr. Christophe Lescop [email protected] Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France) Jochen Autschbach, Department of Chemistry, University at Buffalo, State University of New York, Buffalo, NY 14260 (USA) Jeanne Crassous, Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France) Christophe Lescop, Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France) Régis Réau, Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France)Search for more papers by this authorProf. Régis Réau, Corresponding Author Prof. Régis Réau [email protected] Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France) Jochen Autschbach, Department of Chemistry, University at Buffalo, State University of New York, Buffalo, NY 14260 (USA) Jeanne Crassous, Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France) Christophe Lescop, Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France) Régis Réau, Sciences Chimiques de Rennes UMR 6226 CNRS, Université de Rennes 1, 35042 Rennes Cedex (France)Search for more papers by this author First published: 10 January 2013 https://doi.org/10.1002/anie.201207251Citations: 39 † Financial supports: V.V. thanks the “Région Bretagne” for a CREATE fellowship. Financial support from the CNRS, University of Rennes 1, ANR (12-BS07-0004-METALHEL-01) and the National Science Foundation (CHE 0952253). J.A. and M.S. thank the Center for Computational Research (CCR) at the University at Buffalo. M.S. acknowledges the Foundation for Polish Science (“START” stipend for young researchers) and the Ministry of Science and Higher Education in Poland (“Mobility Plus” program). Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Combining helicate and helicene chemistry: Pentadentate phosphole-pyridine helicands (see scheme) coordinated to CuI or AgI centers afford configurationally stable double-stranded helicates bearing multiple bridging-phosphane coordination modes. Similarly enantiomerically pure helicene-grafted helicands afford enantiopure helicates. Citing Literature Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Filename Description anie_201207251_sm_miscellaneous_information.pdf4.3 MB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume52, Issue7February 11, 2013Pages 1968-1972 RelatedInformation
Publication Year: 2013
Publication Date: 2013-01-10
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']
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Cited By Count: 41
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