An Air‐Stable Oxyallyl Radical Cation

Name: An Air‐Stable Oxyallyl Radical Cation
Uploaded: 2013-05-29

David Martín; Curtis E. Moore; Arnold L. Rheingold; Guy Bertrand

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ID: W2133276674
Title: An Air‐Stable Oxyallyl Radical Cation
Abstract: Angewandte Chemie International EditionVolume 52, Issue 27 p. 7014-7017 Communication An Air-Stable Oxyallyl Radical Cation† Dr. David Martin, Dr. David Martin UCSD-CNRS Joint Research Laboratory (UMI 3555), Department of Chemistry and Biochemistry, University of California San Diego, La Jolla, CA 92093-0343 (USA) http://bertrandgroup.ucsd.eduSearch for more papers by this authorDr. Curtis E. Moore, Dr. Curtis E. Moore UCSD Crystallography Facility, Department of Chemistry and Biochemistry, University of California San Diego, La Jolla, CA 92093-0343 (USA)Search for more papers by this authorArnold L. Rheingold, Arnold L. RheingoldSearch for more papers by this authorProf. Guy Bertrand, Corresponding Author Prof. Guy Bertrand [email protected] UCSD-CNRS Joint Research Laboratory (UMI 3555), Department of Chemistry and Biochemistry, University of California San Diego, La Jolla, CA 92093-0343 (USA) http://bertrandgroup.ucsd.eduUCSD-CNRS Joint Research Laboratory (UMI 3555), Department of Chemistry and Biochemistry, University of California San Diego, La Jolla, CA 92093-0343 (USA) http://bertrandgroup.ucsd.eduSearch for more papers by this author Dr. David Martin, Dr. David Martin UCSD-CNRS Joint Research Laboratory (UMI 3555), Department of Chemistry and Biochemistry, University of California San Diego, La Jolla, CA 92093-0343 (USA) http://bertrandgroup.ucsd.eduSearch for more papers by this authorDr. Curtis E. Moore, Dr. Curtis E. Moore UCSD Crystallography Facility, Department of Chemistry and Biochemistry, University of California San Diego, La Jolla, CA 92093-0343 (USA)Search for more papers by this authorArnold L. Rheingold, Arnold L. RheingoldSearch for more papers by this authorProf. Guy Bertrand, Corresponding Author Prof. Guy Bertrand [email protected] UCSD-CNRS Joint Research Laboratory (UMI 3555), Department of Chemistry and Biochemistry, University of California San Diego, La Jolla, CA 92093-0343 (USA) http://bertrandgroup.ucsd.eduUCSD-CNRS Joint Research Laboratory (UMI 3555), Department of Chemistry and Biochemistry, University of California San Diego, La Jolla, CA 92093-0343 (USA) http://bertrandgroup.ucsd.eduSearch for more papers by this author First published: 29 May 2013 https://doi.org/10.1002/anie.201302841Citations: 63 † D.M. and G.B. acknowledge financial support from the NSF (CHE-1112133 and CHE-1316956), and Maria Angelella and Michael Tauber for assistance with ESR experiments. D.M. acknowledges the Extreme Science and Engineering Discovery Environment (XSEDE), which is supported by NSF (OCI-1053575). Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Easy does it! Simply take two carbenes, add carbon monoxide, then HCl, and open the flask to air, and an oxyallyl radical cation is formed. Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Filename Description anie_201302841_sm_miscellaneous_information.pdf409.4 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References 1 1aA. Igau, H. Grützmacher, A. Baceiredo, G. Bertrand, J. Am. Chem. Soc. 1988, 110, 6463–6466; 10.1021/ja00227a028 CASWeb of Science®Google Scholar 1bA. J. Arduengo III, R. L. Harlow, M. Kline, J. Am. Chem. Soc. 1991, 113, 361–363. 10.1021/ja00001a054 CASWeb of Science®Google Scholar 2 2a N-Heterocyclic Carbenes in Transition Metal Catalysis (Ed.: ), Springer, Amsterdam, 2007; Google Scholar 2bF. E. 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Publication Year: 2013
Publication Date: 2013-05-29
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']

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664, 684, 689, 705, 722, 737, 752, 760, 780, 805, 830, 855, 875, 904, 946, 988, 1026, 1063, 1072, 1086, 1121, 1154, 1187, 1212, 1232, 1254, 1259, 1283, 1297, 1310, 1334, 1345, 1362, 1368, 1385, 1401, 1422, 1457, 1479, 1495, 1517, 1534, 1557, 1577, 1601, 1621, 1640, 1658, 1706, 1715, 1732, 1754, 1770, 1791, 1824, 1851, 1867, 1891, 1920, 1940, 1963, 1993, 2025, 2047, 2066, 2097, 2115, 2143, 2160, 2196, 2223, 2248, 2267, 2289, 2310, 2327, 2352], '1bA.': [546], 'Arduengo': [548, 1946], 'III,': [549, 969, 1947], 'R.': [550, 627, 840, 890, 922, 954, 972, 1004, 1050, 1262, 1313, 1349, 1424, 1543, 1567, 1585, 1801, 1854, 1996, 2030, 2210, 2251, 2291], 'Harlow,': [552], 'M.': [553, 585, 642, 692, 708, 710, 808, 813, 835, 860, 880, 884, 888, 911, 963, 995, 1033, 1100, 1102, 1125, 1126, 1132, 1160, 1161, 1165, 1261, 1312, 1427, 1499, 1545, 1662, 1736, 1775, 1799, 1802, 1808, 1810, 1898, 1904, 1923, 2228, 2269, 2275], 'Kline,': [554], '1991,': [559, 1225, 1725], '113,': [560, 1226], '361–363.': 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797, 938, 1018, 1179, 1204, 1274, 1325, 1698, 1985, 2017, 2089, 2135], '47,': [600], '3122–3172;': [601], '10.1002/anie.200703883': [602], 'CASPubMedWeb': [603, 620, 636, 661, 702, 719, 734, 749, 777, 802, 827, 872, 943, 985, 1023, 1060, 1118, 1151, 1184, 1209, 1251, 1359, 1476, 1514, 1531, 1574, 1703, 1767, 1788, 1821, 1848, 1888, 1937, 1990, 2022, 2044, 2063, 2094, 2112, 2140, 2157, 2245, 2349], '2cS.': [607], 'Díez-González,': [608], 'N.': [609, 1564, 1805, 2119], 'Marion,': [610], 'S.': [611, 838, 894, 1093, 1239, 1373, 1433, 1520, 1522, 1539, 1642, 1661, 1674, 1739, 1778, 1833, 2226, 2235, 2338], 'P.': [612, 765, 958, 970, 1030, 1031, 1036, 1076, 1108, 1141, 1156, 1350, 1426, 1440, 1444, 1460, 1540, 1734, 2052], 'Nolan,': [613], 'Rev.': [615, 631], '2009,': [616, 1079, 1114, 1690, 1699, 2108], '109,': [617, 1845], '3612–3676;': [618], '10.1021/cr900074m': [619], '2dG.': [624], 'Vougioukalakis,': [626], 'Grubbs,': [629], '2010,': [632, 648, 657, 773, 789, 798, 823, 1147, 1860, 1913, 2059], '1746–1787;': [634], '10.1021/cr9002424': [635], '2eM.': [640], 'Melaimi,': [641, 709, 814], 'Soleilhavoup,': [643, 693, 711], '122,': [649, 790], '8992–9032;': [650], '10.1002/ange.201000165': [651], '49,': [658, 799, 2154], '8810–8849;': [659], '10.1002/anie.201000165': [660], '2f': [665], 'Carbenes:': [667], 'From': [668], 'Curiosities': [670], 'Efficient': [672], 'Synthetic': [673], 'Tools': [674], 'Royal': [677], 'Society': [678], 'Chemistry,': [680], 'Cambridge,': [681], '2011.': [682], '3For': [685], 'reviews,': [686], 'see:': [687, 1070, 1257, 1366, 1875], '3aD.': [690], 'Sci.': [697, 847, 1912], '2011,': [698, 715, 745, 848, 868, 1171, 1180, 1355, 1817, 1933], '2,': [699, 774, 849], '389–399;': [700], '10.1039/C0SC00388C': [701], '3bD.': [706], 'Organometallics': [714, 896, 1078], '30,': [716], '5304–5313;': [717], '10.1021/om200650x': [718], '3cY.': [723], 'Wang,': [724, 739, 951], 'Robinson,': [727, 742, 976], 'Dalton': [728], 'Trans.': [729, 1650, 2216], '2012,': [730, 897, 1194, 1205, 2127, 2136], '41,': [731], '337–345;': [732], '10.1039/C1DT11165E': [733], '3dY.': [738], 'Inorg.': [743, 1054], '50,': [746, 1181], '12326–12337.': [747], '10.1021/ic200675u': [748], '4For': [753], 'isolated': [754], 'carbene': [755], 'main-group-element': [756], 'centered': [757], 'radicals:': [758], '4aO.': [761], 'Back,': [762, 807, 832], 'B.': [763, 783, 815, 833, 858, 879, 924, 960, 1000, 1044, 1372, 1546, 1971, 2001, 2033, 2072, 2121, 2270], 'Donnadieu,': [764, 784, 816, 834, 859, 1972, 2002, 2034, 2073, 2122], 'Parameswaran,': [766], 'Frenking,': [768, 812, 843, 864, 915, 999, 1910, 1928], 'Nat.': [771], '369–373;': [775], '10.1038/nchem.617': [776], '4bR.': [781], 'Kinjo,': [782, 857], '6066–6069;': [791], '10.1002/ange.201002889': [792], '5930–5933;': [800], '10.1002/anie.201002889': [801], '4cO.': [806], 'Celik,': [810, 862], '132,': [824, 1148], '10262–10263;': [825], '10.1021/ja1046846': [826], '4dO.': [831], 'von': [836, 1905], 'Hopffgarten,': [837, 1906], 'Klein,': [839], 'Tonner,': [841], '858–861;': [850], '10.1039/c1sc00027f': [851], '4eR.': [856], '333,': [869], '610–613;': [870], '10.1126/science.1207573': [871], '4fP.': [876], 'W.': [877, 909, 993, 1039, 1219, 1682, 1685, 1902, 2049, 2055, 2074, 2075, 2099, 2102], 'Percival,': [878], 'McCollum,': [881], 'J.-C.': [882], 'Brodovitch,': [883], 'Driess,': [885], 'Mitra,': [887], 'Mozafari,': [889], 'West,': [891], 'Y.': [892, 948, 950, 952, 1967, 2003, 2070, 2230], 'Xiong,': [893], 'Yao,': [895], '31,': [898], '2709–2714;': [899], '10.1021/om200966p': [900], '4gK.': [905], 'Mondal##,': [907], 'Roesky,': [910, 994, 1040], 'Schwarzer,': [913, 997], 'I.': [916, 1285, 2232], 'Tkach,': [917], 'Wolf,': [919, 1003, 1049], 'D.': [920, 926, 1006, 1052, 1107, 1140, 1190, 1215, 1429, 1504, 1667, 1679, 1807, 1900, 1949, 1951, 1997, 2031, 2147, 2202, 2294], 'Kratzert,': [921], 'Herbst-Irmer,': [923, 1005, 1051], 'Niepötter,': [925, 1001, 1045], 'Stalke,': [927, 1007, 1053], '2013,': [930, 939, 981, 1010, 1019, 1056, 2153], '125,': [931, 1011, 2242], '1845–1850;': [932], '10.1002/ange.201204487': [933], '1801–1805;': [941], '10.1002/anie.201204487': [942], '4hM.': [947], 'Abraham,': [949], 'Xie,': [953], 'Gilliard,': [956], 'Jr.,': [957, 1405, 1581, 1758], 'Wei,': [959], 'Vaccaro,': [962], 'K.': [964, 1237, 1390, 1437, 1439, 1588, 1804, 1828, 1831, 1835, 1880, 1948, 2296], 'Johnson,': [965], 'F.': [967, 1075, 1218, 1235, 1644, 1741, 1794], 'Schaefer': [968], 'v.': [971], 'Schleyer,': [973], '135,': [982], '2486–2488;': [983], '10.1021/ja400219d': [984], '4iK.': [989], 'Mondal,': [991, 1029], '3036–3040;': [1012], '10.1002/ange.201208307': [1013], '2963–2967;': [1021], '10.1002/anie.201208307': [1022], '4jK.': [1027], 'Samuel,': [1032], 'Tretiakov,': [1034], 'Singh,': [1037], 'Stückl,': [1043], 'Carl,': [1047], '4736–4743.': [1058], '10.1021/ic400357p': [1059], '5For': [1064], 'transient': [1065], 'persistent': [1067], 'diaminocarbene–BR2⋅': [1068], 'adducts,': [1069], '5aT.': [1073], 'Matsumoto,': [1074], 'Gabbaï,': [1077], '28,': [1080], '4252–4253;': [1081], '10.1021/om900476g': [1082], '5bS.-H.': [1087], 'Ueng,': [1088, 1137], 'Solovyev,': [1090, 1139, 1159], 'X.': [1091, 1677], 'Yuan,': [1092], 'Geib,': [1095], 'Fensterbank,': [1097, 1129, 1164], 'Lacôte,': [1099, 1131, 1168], 'Malacria,': [1101, 1133, 1166], 'Newcomb,': [1103], 'Walton,': [1106, 1124], 'Curran,': [1109, 1142, 1157], '131,': [1115, 2109], '11256–11262;': [1116], '10.1021/ja904103x': [1117], '5cJ.': [1122], 'Brahmi,': [1127, 1162], 'Q.': [1134], 'Chu,': [1135], 'S.-H.': [1136], '2350–2358;': [1149], '10.1021/ja909502q': [1150], '5dD.': [1155], '123,': [1172], '10476–10500;': [1173], '10.1002/ange.201102717': [1174], '10294–10317.': [1182], '10.1002/anie.201102717': [1183], '6A.': [1188], 'Grossmann,': [1189], 'Enders,': [1191], '124,': [1195, 1764, 2128], '320–332;': [1196], '10.1002/ange.201105415': [1197], 'PubMedWeb': [1198], '51,': [1206, 2137], '314–325.': [1207], '10.1002/anie.201105415': [1208], '7F.': [1213], 'Turecek,': [1214], 'Drinkwater,': [1217], 'McLafferty,': [1220], '5950–5958.': [1227], '10.1021/ja00016a005': [1228], '8H.': [1233], 'Ikeda,': [1234], 'Tanaka,': [1236], 'Akiyama,': [1238], 'Tero-Kubota,': [1240], 'T.': [1241, 1541, 1683, 1718, 1720, 1738, 1777], 'Miyashi,': [1242, 1721], '2004,': [1247], '126,': [1248], '414–415.': [1249], '10.1021/ja038068c': [1250], '9For': [1255], 'reviews': [1256], '9aH.': [1260], 'Hoffmann,': [1263, 1314], '1973,': [1266, 1276, 2303], '85,': [1267], '877–894;': [1268], '10.1002/ange.19730852002': [1269], 'CASGoogle': [1270, 1321, 2222], 'Engl.': [1275, 1326], '12,': [1277, 1304], '819–835;': [1278], '10.1002/anie.197308191': [1279], 'Web': [1280, 1331, 2286], '9bD.': [1284], 'Schuster,': [1286], 'Acc.': [1287, 1300], 'Res.': [1289, 1302], '1978,': [1290, 1378], '11,': [1291], '65–73;': [1292], '10.1021/ar50122a003': [1293], '9cR.': [1298], 'Noyori,': [1299], '1979,': [1303], '61–66;': [1305], '10.1021/ar50134a003': [1306], '9dH.': [1311], '1984,': [1317, 1327], '96,': [1318], '29–48;': [1319], '10.1002/ange.19840960106': [1320], '23,': [1328, 1861], '1–19;': [1329], '10.1002/anie.198400013': [1330], '9eJ.': [1335], 'Mann,': [1336], 'Tetrahedron': [1337, 1392, 1548, 1954], '1986,': [1338], '42,': [1339], '4611–4659;': [1340], '10.1016/S0040-4020(01)82046-9': [1341], '9fA.': [1346], 'Lohse,': [1348], 'Hsung,': [1351], 'Eur.': [1353, 1485], '17,': [1356], '3812–3822.': [1357], '10.1002/chem.201100260': [1358], '10For': [1363], 'representative': [1364], 'examples,': [1365], '10aT.': [1369], 'Chan,': [1371], 'Ong,': [1374], 'Org.': [1376, 1470, 1487, 1508, 1524, 1723, 1858, 1882, 2038], '43,': [1379], '2994–3001;': [1380], '10.1021/jo00409a013': [1381], '10bS.': [1386], 'Kim,': [1388], 'Cha,': [1391, 1589], 'Lett.': [1393, 1549, 1883, 1955], '29,': [1395, 1551], '5613–5616;': [1396], '10.1016/S0040-4039(00)80826-6': [1397], '10cB.': [1402], 'Hess,': [1404, 1580, 1757], 'U.': [1406, 1925, 2297], 'Eckart,': [1407], 'Fabian,': [1410, 1853], '1998,': [1415, 1652, 2282], '12310–12315;': [1417], '10.1021/ja9821652': [1418], '10dA.': [1423], 'Matlin,': [1425], 'Lahti,': [1428], 'Appella,': [1430], 'Straumanis,': [1432], 'Lin,': [1434], 'Patel,': [1436], 'Jin,': [1438], 'Schrieber,': [1441], 'Pauls,': [1443], 'Raulerson,': [1445], '1999,': [1450, 1594], '121,': [1451, 1595, 1691], '2164–2173;': [1452], '10.1021/ja984128g': [1453], '10eS.': [1458], 'Grecian,': [1459], 'Desai,': [1461], 'Mossman,': [1463], 'Poutsma,': [1466], 'Aubé,': [1468], '2007,': [1472, 1489, 1510, 2009, 2018, 2040], '72,': [1473, 1511, 2041], '9439–9447;': [1474], '10.1021/jo0711034': [1475], '10fH.': [1480], 'Zimmerman,': [1482], 'V.': [1483, 1837, 1952], 'Suryanarayan,': [1484], '4091–4102;': [1490], '10.1002/ejoc.200700456': [1491], '10gA.': [1496], 'Moiseev,': [1498], 'Abe,': [1500], 'O.': [1502, 1560, 2200], 'Danilov,': [1503], 'Neckers,': [1506], '2777–2784;': [1512], '10.1021/jo062259r': [1513], '10hN.': [1518], 'Tsuchida,': [1519], 'Yamazaki,': [1521], 'Yamabe,': [1523], 'Biomol.': [1525], '6,': [1528], '3109–3117.': [1529], '10.1039/b806577b': [1530], '11': [1535], '11aE.': [1536], 'Corey,': [1538], 'Matsuda,': [1542], 'Nagata,': [1544], 'Cleaver,': [1547], '2555–2558;': [1552], '10.1016/S0040-4039(00)86110-9': [1553], '11bR.': [1558], 'Koljak,': [1559], 'Boutaud,': [1561], 'B.-H.': [1562], 'Shieh,': [1563], 'Samel,': [1565], 'Brash,': [1568, 1586], '1997,': [1570], '277,': [1571], '1994–1996;': [1572], '10.1126/science.277.5334.1994': [1573], '11cB.': [1578], 'Smentek,': [1583], '5603–5604.': [1596], '10.1021/ja990728j': [1597], '12': [1602], '12aM.': [1603], 'Cordes,': [1606, 1625], 'Berson,': [1609, 1628], '1992,': [1614], '114,': [1615], '11010–11011;': [1616], '10.1021/ja00053a076': [1617], '12bM.': [1622], '1996,': [1633, 2320], '118,': [1634, 2082, 2321], '6241–6251;': [1635], '10.1021/ja960481f': [1636], '12cT.': [1641], 'Sorensen,': [1643, 1740, 1779], 'Sun,': [1645, 1742], 'Perkin': [1649, 2215], '1053–1061;': [1653], '10.1039/a706265f': [1654], '12dT.': [1659], 'Ichino,': [1660], 'Villano,': [1663], 'Gianola,': [1666], 'Goebbert,': [1669], 'Velarde,': [1671], 'Sanov,': [1673], 'Blanksby,': [1676], 'Zhou,': [1678], 'Hrovat,': [1681], 'Borden,': [1684], 'Lineberger,': [1687], '8661–8663;': [1692], '10.1002/ange.200904417': [1693], '48,': [1700], '8509–8511.': [1701], '10.1002/anie.200904417': [1702], '13For': [1707], 'attempts': [1708], 'at': [1709], 'generating': [1710], 'observing': [1712], 'oxyallyls:': [1713], '13aT.': [1716], 'Hirano,': [1717], 'Kumagai,': [1719], '56,': [1726], '1907–1914;': [1727], '10.1021/jo00005a044': [1728], '13bA.': [1733], 'Masters,': [1735], 'Parvez,': [1737, 1776], '1994,': [1747], '116,': [1748], '2804–2811;': [1749], '10.1021/ja00086a013': [1750], '13cB.': [1755], '2002,': [1763], '920–921;': [1765], '10.1021/ja0172823': [1766], '13dS.': [1771], 'Bhargava,': [1772], 'Hou,': [1774], '2005,': [1784, 1844, 1977, 1986], '127,': [1785], '3704–3705.': [1786], '10.1021/ja043646q': [1787], '14G.': [1792], 'Kuzmanich,': [1793], 'Spänig,': [1795], 'C.-K.': [1796], 'Tsai,': [1797], 'Um,': [1800], 'Hoekstra,': [1803], 'Houk,': [1806], 'Guldi,': [1809], 'Garcia-Garibay,': [1812], '133,': [1818, 1934], '2342–2345.': [1819], '10.1021/ja109494b': [1820], '15': [1825], '15aC.': [1826], 'Prabhakar,': [1827], 'Yesudas,': [1829], 'Chaitanya,': [1832], 'Sitha,': [1834], 'Bhanuprakash,': [1836], 'Rao,': [1839], 'Phys.': [1841, 1857, 2278], 'A': [1843], '8604–8616;': [1846], '10.1021/jp0516184': [1847], '15bJ.': [1852], 'Peichert,': [1855], '1137–1145.': [1862], '10.1002/poc.1684': [1863], '16For': [1868], 'experimental': [1869], 'trapping': [1870], 'elusive': [1872], 'amino-substituted': [1873], 'oxyallyls,': [1874], 'Myers,': [1878], 'Barbay,': [1881], '2001,': [1884], '3,': [1885], '425–428.': [1886], '10.1021/ol006931x': [1887], '17U.': [1892], 'Siemeling,': [1893, 1926], 'Färber,': [1895], 'Bruhn,': [1897], 'Leibold,': [1899, 1924], 'Selent,': [1901], 'Baumann,': [1903], 'Goedecke,': [1908, 1922], '1,': [1914, 2357], '697–704.': [1915], '10.1039/c0sc00451k': [1916], '18C.': [1921], '3557–3569.': [1935], '10.1021/ja109812r': [1936], '19D.': [1941], 'Dixon,': [1943], 'Dobbs,': [1950], 'Khasnis,': [1953], '1995,': [1956], '36,': [1957], '645–648.': [1958], '10.1016/0040-4039(94)02341-8': [1959], '20': [1964], '20aV.': [1965], 'Lavallo,': [1966, 2069], 'Canac,': [1968, 2004, 2071], 'Prasang,': [1970], '117,': [1978], '5851–5855;': [1979], '10.1002/ange.200501841': [1980], '44,': [1987], '5705–5709;': [1988], '10.1002/anie.200501841': [1989], '20bR.': [1994], 'Jazzar,': [1995, 2027], 'Dewhurst,': [1998, 2032], 'J.-B.': [1999, 2028], 'Bourg,': [2000, 2029], '119,': [2010], '2957–2960;': [2011], '10.1002/ange.200605083': [2012], '46,': [2019, 2060], '2899–2902;': [2020], '10.1002/anie.200605083': [2021], '20cR.': [2026], '3492–3499.': [2042], '10.1021/jo0703909': [2043], '21T.': [2048], 'Hudnall,': [2050, 2100], 'Moerdyk,': [2053], 'Bielawski,': [2056, 2103], 'Commun.': [2058, 2152], '4288–4290.': [2061], '10.1039/c0cc00638f': [2062], '22': [2067], '22aV.': [2068], 'Schoeller,': [2076], '2006,': [2081, 2090, 2345], '3568–3571;': [2083], '10.1002/ange.200600987': [2084], '45,': [2091], '3488–3491;': [2092], '10.1002/anie.200600987': [2093], '22bT.': [2098], '16039–16041.': [2110], '10.1021/ja907481w': [2111], '23': [2116], '23aD.': [2117], 'Lassauque,': [2120], '6276–6279;': [2129], '10.1002/ange.201202137': [2130], '6172–6175;': [2138], '10.1002/anie.201202137': [2139], '23bM.': [2144], 'Lopez-Gomez,': [2146], '4483–4485.': [2155], '10.1039/c3cc41279b': [2156], '24CCDC': [2161], '932572': [2162], '(4),': [2163], '932573': [2164], '(5),': [2165], '932574': [2166], '(d,l-6),': [2167], '932575': [2169], '(meso-6),': [2170], 'contain': [2171], 'supplementary': [2173], 'crystallographic': [2174], 'data': [2175, 2180], 'paper.': 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'10.1063/1.556020': [2285], '27cL.': [2290], 'Mahoney,': [2292], 'Mendenhal,': [2295], 'Ingold,': [2298], '95,': [2304], '8610–8614;': [2305], '10.1021/ja00807a018': [2306], '27dF.': [2311], 'Bordwell,': [2313], 'W.-Z.': [2314], 'Liu,': [2315], '10819–10823.': [2322], '10.1021/ja961469q': [2323], '28Experimental': [2328], 'EPR': [2329], 'spectra': [2330], 'were': [2331], 'fitted': [2332], 'EasySpin': [2335], 'simulation': [2336], 'package:': [2337], 'Stoll,': [2339], 'Schweiger,': [2341], 'Magn.': [2343], 'Reson.': [2344], '178,': [2346], '42–55.': [2347], '10.1016/j.jmr.2005.08.013': [2348], 'Citing': [2353], 'Literature': [2354], 'Volume52,': [2355], 'Issue27July': [2356], '2013Pages': [2358], 'ReferencesRelatedInformation': [2360]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W2133276674', 'counts_by_year': [{'year': 2024, 'cited_by_count': 3}, {'year': 2023, 'cited_by_count': 3}, {'year': 2022, 'cited_by_count': 5}, {'year': 2021, 'cited_by_count': 8}, {'year': 2020, 'cited_by_count': 5}, {'year': 2019, 'cited_by_count': 3}, {'year': 2018, 'cited_by_count': 10}, {'year': 2017, 'cited_by_count': 8}, {'year': 2016, 'cited_by_count': 7}, {'year': 2015, 'cited_by_count': 8}, {'year': 2014, 'cited_by_count': 5}, {'year': 2013, 'cited_by_count': 4}], 'updated_date': '2024-09-24T04:29:59.462421', 'created_date': '2016-06-24'}

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