Title: Charge Transfer Spectra of some Gold(III) Complexes
Abstract: Tetrahalo complexes of Au(III) show two intense bands in the ultraviolet. These are interpreted as charge-transfer bands; the transfer is from halogen p to gold d orbitals. The two bands are associated with pσ→dx2—y2 and pπ→dx2—y2 transitions. The iodo complex undergoes spontaneous reduction; reason for this is discussed. The ethylenediamine complexes of Au(III) also exhibit interesting charge-transfer phenomenon.
Publication Year: 1961
Publication Date: 1961-12-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 133
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