Title: A novel 2D layer structural compound constructed from tetra-capped pseudo-Keggin heteropolytungstates interacting with copper coordination fragments:
Abstract: A novel polyoxometalate [Cu(en)2(H2O)]2[Cu(en)2]2 [AsW9V7O44] · 2H2O (1) has been hydrothermally synthesized and characterized by elemental analysis, IR spectrum, XPS spectrum and single crystal X-ray diffraction analysis. It is the first example of two-dimensional layer structure constructed from four vanadium-capped pseudo-Keggin tungstates. The study of the magnetic susceptibility of 1 demonstrates the presence of ferromagnetic interactions.
Publication Year: 2007
Publication Date: 2007-09-15
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 12
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