Title: A new Keggin-templated heterometal-oxide-based organic–inorganic hybrid compound
Abstract: Abstract A new Keggin-ion-templated, heterometal-oxide-based organic–inorganic hybrid compound 1 [H+]4[MnIV(bpy)2MnII(bpy)2Mo(bpy)O5]2[bpy]2[PMo11VO40]2·4H2O (bpy = 2,2′-bipyridine) has been hydrothermally synthesized and characterized by elemental analysis, IR spectroscopy, TG analysis, XPS spectrum and single-crystal X-ray diffraction. The cationic host of compound 1 represents Z-shaped hexa-metal chain of overall formula [Mn4Mo2O10(bipy)10]4+ incorporating manganese in both the +II and +IV oxidation states. The electrochemical and magnetic properties of compound 1 were also investigated.
Publication Year: 2014
Publication Date: 2014-01-31
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 5
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