Title: Diastereoselective addition of 2-butenylmetal “ate” complexes to aromatic ketones mediated by Cr (CO)3 complexation
Abstract: The reaction of 2-butenylmagnesium chloride with chromium complexes of aromatic ketones in the presence of trialkylaluminum produces predominantly the anti-adducts. The resulting benzylic hydroxyl group of the adducts is stereospecifically substituted with some nucleophiles.
Publication Year: 1986
Publication Date: 1986-01-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 20
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