Title: Silia<i>Cat</i> Diphenylphosphine Palladium(II) Catalyzed Borylation of Aryl Halides
Abstract: Abstract We investigate the heterogeneously catalyzed direct synthesis of boronic acid pinacol esters using a wide range of aryl chlorides, bromides, and iodides, and bis(pinacolato)diboron as the borylating agent over the sol–gel entrapped Silia Cat diphenylphosphine palladium(II) catalyst. Optimization of the reaction conditions, scale‐up of the optimized process, and analysis of palladium leaching enabled us to establish a new selective route for direct access to a diverse set of boronic acid pinacol esters.
Publication Year: 2014
Publication Date: 2014-03-03
Language: en
Type: article
Indexed In: ['crossref']
Access and Citation
Cited By Count: 20
AI Researcher Chatbot
Get quick answers to your questions about the article from our AI researcher chatbot